Preparation and I. R. studies of Ethyl(n‐Propyl)Tin Dichloride and its Adducts with Nitrogen Donors

Complexes of methylethyltin dichloride with 3‐, 4‐picolines, isoquinoline and benzyl amine, of ethyl(n‐propyl) tin dichloride with pyridine, 3‐picoline and isoquinoline and of n‐propyl (n‐butyl)tin dichloride with isoquinoline, n‐propyl amine and benzyl amine have been prepared and their stoichiometries established from their tin and chlorine contents. I.R. measurements (4000–200 cm−1) suggest that in all the hexa‐coordinated complexes of methylethyltin dichloride, the chlorines are in cis‐position. In case of hexa‐coordinated complexes of ethyl(n‐propyl)‐ and n‐propyl (n‐butyl) tin dichlorides, however, the multiple splitting of tin‐chlorine stretching band may also be due to the presence of conformational isomers. The conductance measurements have also been carried out to determine their ionic character.

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Mixed dialkyltin(IV) trifluoroacetates

Midha

Verma

Brown

et al. 1983

Monatsh Chem

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Preparation and I. R. studies of Ethyl(n‐Propyl)Tin Dichloride and its Adducts with Nitrogen Donors

Cited by 8 publications

References 7 publications

ChemInform Abstract: PREPARATION AND IR STUDIES OF ETHYL(N‐PROPYL)TIN DICHLORIDE AND ITS ADDUCTS WITH NITROGEN DONORS

ChemInform Abstract: PREPARATION AND IR STUDIES OF ETHYL(N‐PROPYL)TIN DICHLORIDE AND ITS ADDUCTS WITH NITROGEN DONORS

Preparation and I.R. Studies of the Complexes of Methylethyl‐, EthyI(n‐propyl)‐ and n‐Propyl(n‐butyl)tin Dichlorides with Some Nitrogen Donors

Mixed dialkyltin(IV) trifluoroacetates

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