Preliminary Study on The Development of Preconcentration Method of Cu(II), Co(II), Ni(II), and Cr(III) Ions in Water Samples Using Nanomagnetite Coated by Carboxymethyl kappa-Carrageenan (CMKC)

Abstract

Flame Atomic Adsorption Spectrophotometry (FAAS) is one of the instruments that is often used to determine metal ion concentration in solution. FAAS uses simple operational procedure for metal ions concentration determination and produces accurate metal ion concentrations. Unfortunately, the accuracy of metal ion determination test decreases if the concentration of metal ions is too low, whereas the threshold for metal ions in drinking water is very low. Preconcentration is a method for increasing the concentration of metal ions in sample. An effective preconcentration method needs to be studied to improve the accuracy in the determination of metal ions concentration in water at low concentration using FAAS. This research aims to determine the effectiveness of metal ions preconcentration in water samples using nanomagnetite coated by CMKC. The research was conducted in four stages, 1) synthesis of nanomagnetite coated by CMKC; 2) preconcentration of samples containing Cu(II), Co(II), Ni(II), and Cr(III); 3) measurement of metal ion concentration with FAAS; 4) effectivity of preconcentration process and preconcentration optimum conditions. The result showed that nanomagnetite coated by CMKC can be used to preconcentration of metal ions Cu(II), Co(II), Ni(II), and Cr(III) in water samples by utilizing desorption-adsorption mechanism. Desorption was done using 0.1 N HNO3 as a desorption solvent without variation in concentration and desorption time preconcentration optimum conditions for each metal ion were as follows, adsorption condition of Ni(II) was pH 7 and 60 minutes; Cr(III) was pH 7 and 40 minutes; Co(II) was pH 7 and 60 minutes; Cu(II) pH 6 and 40 minutes. The effectiveness of preconcentration at optimum conditions for each metal ions are: %Cr(III) > %Cu(II) > % Co(II) > %Ni(II), successively.

Synthesis of Nanomagnetite/Crosslinked Carboxymethyl kappa Carrageenan Nickel Imprinted Composite

“…The previous researchers has developed the use of nano magnetite/carboxymethyl kcarrageenan(CMKC) composite as an adsorbent for Cr(III), Cu(II), Ni(II) and Co(II) metal ions [15], biomaterial adsorbent [16], metal ion preconcentration media in samples containing single ions Cu(II), Co(II), Ni(II) and Cr(II) [17], a mixture of metal ions Ni(II) and Cr(III) [18], a mixture of Pb(II) and Cu(II) [19]. Some previous research results show that nano magnetite/CMKC can adsorb various metals simultaneously.…”