Porous carbon nanofiber derived from a waste biomass as anode material in lithium-ion batteries

Tao, Lei; Huang, Yuanbo; Zheng, Yunwu; Yang, Xiaoqin; Liu, Can; Di, Mingwei; Larpkiattaworn, Siriporn; Nimlos, Mark R.; Zheng, Zhifeng

doi:10.1016/j.jtice.2018.07.005

Cited by 65 publications

(39 citation statements)

References 44 publications

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“…Many macropores maintain their initial shapes and sizes after cycling at such a high current density, which is favourable for obtaining good cycling stability. [27,28,38,[44][45][46]53,[60][61][62] compares the electrochemical performance of the current study with the previously reported works. It can be seen that the electrochemical performance of the HPC anode is superior to most of reported biomass-based carbon materials.…”

Section: Resultssupporting

confidence: 57%

“…After 5 min, the brightness of the LED bulb decreases obviously compared with its initial state, while the bulb still can work. Table 1 [27,28,38,[44][45][46]53,[60][61][62] compares the electrochemical performance of the current study with the previously reported works. It can be seen that the electrochemical performance of the HPC anode is superior to most of reported biomass-based carbon materials.…”

Section: Resultsmentioning

confidence: 80%

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Hierarchically Porous Carbon Derived from Biomass Reed Flowers as Highly Stable Li-Ion Battery Anode

et al. 2020

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As lithium-ion battery (LIB) anode materials, porous carbons with high specific surface area are highly required because they can well accommodate huge volume expansion/contraction during cycling. In this work, hierarchically porous carbon (HPC) with high specific surface area (~1714.83 m2 g−1) is synthesized from biomass reed flowers. The material presents good cycling stability as an LIB anode, delivering an excellent reversible capacity of 581.2 mAh g−1 after cycling for 100 cycles at a current density of 100 mA g−1, and still remains a reversible capacity of 298.5 mAh g−1 after cycling for 1000 cycles even at 1000 mA g−1. The good electrochemical performance can be ascribed to the high specific surface area of the HPC network, which provides rich and fast paths for electron and ion transfer and provides large contact area and mutual interactions between the electrolyte and active materials. The work proposes a new route for the preparation of low cost carbon-based anodes and may promote the development of other porous carbon materials derived from various biomass carbon sources.

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Section: Resultssupporting

confidence: 57%

Section: Resultsmentioning

confidence: 80%

Hierarchically Porous Carbon Derived from Biomass Reed Flowers as Highly Stable Li-Ion Battery Anode

et al. 2020

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“…The vibrations seen at 2925 cm −1 , 2853 cm −1 , 1457 cm −1 , 1427cm −1 , and 1428 cm −1 are associated with different aliphatic CH groups (CH and CH 2 bonds), as reported previously for carbon nanofibers [25]. The broad peak at 3430 cm −1 is characteristic of O–H stretching from inter- and intramolecular hydrogen bonds, and the peaks at 1652 cm −1 and 1457 cm −1 are characteristic of phenolic resins [26].…”

Section: Resultssupporting

confidence: 73%

Enhanced Electrochemical Response of Diclofenac at a Fullerene–Carbon Nanofiber Paste Electrode

Motoc

Manea

Orha

et al. 2019

Sensors

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The requirements of the Water Framework Directive to monitor diclofenac (DCF) concentration in surface water impose the need to find advanced fast and simple analysis methods. Direct voltammetric/amperometric methods could represent efficient and practical solutions. Fullerene–carbon nanofibers in paraffin oil as a paste electrode (F–CNF) was easily obtained by simple mixing and tested for DCF detection using voltammetric and amperometric techniques. The lowest limit of detection of 0.9 nM was achieved by applying square-wave voltammetry operated under step potential (SP) of 2 mV, modulation amplitude (MA) of 10 mV, and frequency of 25 Hz, and the best sensitivity was achieved by four-level multiple pulsed amperometry (MPA) that allowed in situ reactivation of the F–CNF electrode. The selection of the method must take into account the environmental quality standard (EQS), imposed through the “watchlist” of the Water Framework Directive as 0.1 µg·L−1 DCF. A good improvement of the electroanalytical parameters for DCF detection on the F–CNF electrode was achieved by applying the preconcentration step for 30 min before the detection step, which assured about 30 times better sensitivity, recommending its application for the monitoring of trace levels of DCF. The electrochemical behavior of F–CNF as a pseudomicroelectrode array makes it suitable for practical application in the in situ and real-time monitoring of DCF concentrations in water.

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“…Currently, research is mainly focused on the progress of new cathode and anode materials. In fact, the electrolyte, which ionically connects the electrodes, is a vital factor influencing the performance of batteries . In general, LIBs contain a graphite anode (e.g., mesocarbon microbeads, MCMB) and a cathode formed by a lithium metal oxide (LiMO 2 , e.g., LiCoO 2 ) .…”

Section: Separators For Energy Density Battery Applicationssupporting

confidence: 57%

Separator Membranes for High Energy‐Density Batteries

et al. 2018

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Rechargeable lithium-ion, lithium-sulfur, zinc-air, and redox-flow batteries are the most anticipated multipurpose platforms for future generations of electric vehicles, consumer devices, and portable electronics because of their high-energy density and cost-effective electrochemical energy storage. Over the past decades, a variety of novel separator membranes and electrolytes have been developed to improve rechargeable battery performance while not thoroughly addressing the issue of flammability, safety, and low cycling stability of high-energy-density batteries. This comprehensive review mainly underlines the optimization and modification of porous membranes for battery separator applications, covering four significant types: microporous separators, nonwoven mat separators, polymer electrolyte membranes, and composite membrane separators. Furthermore, the present trends in material selection for batteries are reviewed, and different choices of cathode, anode, separator, and electrolyte materials are discussed, which will also serve as key components to boost the development of next-generation rechargeable batteries.

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Porous carbon nanofiber derived from a waste biomass as anode material in lithium-ion batteries

Cited by 65 publications

References 44 publications

Hierarchically Porous Carbon Derived from Biomass Reed Flowers as Highly Stable Li-Ion Battery Anode

Hierarchically Porous Carbon Derived from Biomass Reed Flowers as Highly Stable Li-Ion Battery Anode

Enhanced Electrochemical Response of Diclofenac at a Fullerene–Carbon Nanofiber Paste Electrode

Separator Membranes for High Energy‐Density Batteries

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