Hierarchically Porous Carbon Derived from Biomass Reed Flowers as Highly Stable Li-Ion Battery Anode

Zhao, Weimin; Wen, Jingjing; Zhao, Yanming; Wang, Zhifeng; Shi, Yaru; Zhao, Yan

doi:10.3390/nano10020346

Cited by 30 publications

(21 citation statements)

References 62 publications

(88 reference statements)

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“…However, the exact composition of biomass precursors is influenced by the biomass species, growing habitat, geographical location, and seasonal changes. Various biomass precursors were investigated, including wheat bran ( Wang et al, 2020 ) avocado seeds ( Yokokura et al, 2020 ), reed flowers ( Zhao et al, 2020 ), cherry pits ( Hernández-Rentero et al, 2020 ), green-tea waste ( Sankar et al, 2019 ), coffee grounds ( Luna-Lama et al, 2019 ), peanut dregs ( Yuan et al, 2019 ), loofah ( Wu et al, 2019 ), jute fiber ( Dou et al, 2019 ), coffee oil ( Kim et al, 2018 ), corn stalks ( Li et al, 2018 ), apple, celery ( Hao et al, 2018 ), wheat flour ( Lim et al, 2017 ), coir pith ( Mullaivananathan et al, 2017 ), orange peel ( Xiang et al, 2017 ), woodchips ( Adams et al, 2016 ), prolifera-green-tide ( Cui et al, 2016 ), wheat stalk ( Zhou et al, 2016 ), coconut oil ( Gaddam et al, 2016 ), rice ( Han et al, 2016 ), and cotton ( Zhu and Akiyama, 2016 ). Cotton, a viable raw material for carbon manufacturing, contains 90–95% cellulose, thus making it one of the most abundant and environmentally favorable biomass materials in nature.…”

Section: Biomass-derived Carbon For Lithium-ion Batteriesmentioning

confidence: 99%

Biomass-Based Silicon and Carbon for Lithium-Ion Battery Anodes

et al. 2022

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Lithium-ion batteries (LIBs) are the most preferred energy storage devices today for many high-performance applications. Recently, concerns about global warming and climate change have increased the need and requirements for LIBs used in electric vehicles, and thus more advanced technologies and materials are urgently needed. Among the anode materials under development, silicon (Si) has been considered the most promising anode candidate for the next generation LIBs to replace the widely used graphite. Si cannot be used as such as the electrode of LIB, and thus, carbon is commonly used to realize the applicability of Si in LIBs. Typically, this means forming a-Si/carbon composite (Si/C). One of the main challenges in the industrial development of high-performance LIBs is to exploit low-cost, environmentally benign, sustainable, and renewable chemicals and materials. In this regard, bio-based Si and carbon are favorable to address the challenge assuming that the performance of the LIB anode is not compromised. The present review paper focuses on the development of Si and carbon anodes derived from various types of biogenic sources, particularly from plant-derived biomass resources. An overview of the biomass precursors, process/extraction methods for producing Si and carbon, the critical physicochemical properties influencing the lithium storage in LIBs, and how they affect the electrochemical performance are highlighted. The review paper also discusses the current research challenges and prospects of biomass-derived materials in developing advanced battery materials.

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Section: Biomass-derived Carbon For Lithium-ion Batteriesmentioning

confidence: 99%

Biomass-Based Silicon and Carbon for Lithium-Ion Battery Anodes

et al. 2022

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“…The hemp-derived carbon with a hierarchically porous structure (Figure 15b 1 ,b 2 ) and partial graphitization in amorphous domains was developed for lithiumion battery with a specific capacity of 210 mAh g −1 at 1.5 A g −1 . Zhao et al [295] synthesized hierarchically porous carbon (HPC) with a high specific surface area (≈1714.83 m 2 g −1 ) from biomass reed flowers. The high specific surface area provided rich and fast paths for electron and ion transfer, delivering a capacity of 581.2 mAh g −1 after 100 cycles at 100 mA g −1 and a capacity of 298.5 mAh g −1 after 1000 cycles at 1000 mA g −1 .…”

Section: Biomass Materialsmentioning

confidence: 99%

“…Zhao et al. [ 295 ] synthesized hierarchically porous carbon (HPC) with a high specific surface area (≈1714.83 m 2 g −1 ) from biomass reed flowers. The high specific surface area provided rich and fast paths for electron and ion transfer, delivering a capacity of 581.2 mAh g −1 after 100 cycles at 100 mA g −1 and a capacity of 298.5 mAh g −1 after 1000 cycles at 1000 mA g −1 .…”

Section: Advanced Energy Storage Materialsmentioning

confidence: 99%

Rechargeable Batteries: Regulating Electronic and Ionic Transports for High Electrochemical Performance

Zhao

Hui

et al. 2021

Adv Materials Technologies

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Rechargeable batteries are serving society and are continuing to develop according to application requirements. Recently, rechargeable batteries with high energy density, power density, stability, and rate performance, as well as low cost have attracted the attention of researchers globally. However, achieving all these merits in a single rechargeable battery system is difficult. Accordingly, many approaches are reported to improve the performance of different energy storage devices. Nevertheless, reports on a general research method to improve the performance of battery systems are still limited. Herein, the current progress of rechargeable batteries and the corresponding opportunities and challenges are summarized. The principles of electrochemical reactions for lead–acid batteries, metal–ion batteries, metal–sulfur batteries, and metal–air batteries are introduced and compared. The technological challenges in the development of rechargeable batteries on the basis of transports of electrons and ions are comprehensively analyzed. In particular, approaches for regulating electronic and ionic transports are comprehensively discussed for the enhancement of electrochemical performance. Some advanced energy storage materials with good electronic and ionic conductivities are also highlighted. Furthermore, several perspectives on potential research directions for the choice and design of high‐performance rechargeable batteries for practical application are proposed.

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“…Recently, research on carbon materials and graphene as anode materials for lithiumion batteries has been conducted [2][3][4]. There are several types of carbon allotropes [5,6], including graphene, graphite, diamond, carbon nanowalls (CNW), carbon nanotubes (CNT), and fullerenes.…”

Section: Introductionmentioning

confidence: 99%

Preparation of Carbon Nanowall and Carbon Nanotube for Anode Material of Lithium-Ion Battery

et al. 2021

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Carbon nanowall (CNW) and carbon nanotube (CNT) were prepared as anode materials of lithium-ion batteries. To fabricate a lithium-ion battery, copper (Cu) foil was cleaned using an ultrasonic cleaner in a solvent such as trichloroethylene (TCE) and used as a substrate. CNW and CNT were synthesized on Cu foil using plasma-enhanced chemical vapor deposition (PECVD) and water dispersion, respectively. CNW and CNT were used as anode materials for the lithium-ion battery, while lithium hexafluorophosphate (LiPF6) was used as an electrolyte to fabricate another lithium-ion battery. For the structural analysis of CNW and CNT, field emission scanning electron microscope (FE-SEM) and Raman spectroscopy analysis were performed. The Raman analysis showed that the carbon nanotube in composite material can compensate for the defects of the carbon nanowall. Cyclic voltammetry (CV) was employed for the electrochemical properties of lithium-ion batteries, fabricated by CNW and CNT, respectively. The specific capacity of CNW and CNT were calculated as 62.4 mAh/g and 49.54 mAh/g. The composite material with CNW and CNT having a specific capacity measured at 64.94 mAh/g, delivered the optimal performance.

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Hierarchically Porous Carbon Derived from Biomass Reed Flowers as Highly Stable Li-Ion Battery Anode

Cited by 30 publications

References 62 publications

Biomass-Based Silicon and Carbon for Lithium-Ion Battery Anodes

Biomass-Based Silicon and Carbon for Lithium-Ion Battery Anodes

Rechargeable Batteries: Regulating Electronic and Ionic Transports for High Electrochemical Performance

Preparation of Carbon Nanowall and Carbon Nanotube for Anode Material of Lithium-Ion Battery

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