1995
DOI: 10.1021/ja00119a010
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Polymeric Self-Assembled Monolayers. 2. Synthesis and Characterization of Self-Assembled Polydiacetylene Mono- and Multilayers

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Cited by 122 publications
(137 citation statements)
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“…Extended tetrathiafulvalene (TTF) analogs have been widely developed in view of increasing the dimensionality of the corresponding conducting materials. [7] However, from a different viewpoint, one can envision taking advantage of the strong p-donor properties of the 1,4-dithiafulvenyl (DTF) group to alter the electronic properties of ex- …”
Section: Methodsmentioning
confidence: 99%
“…Extended tetrathiafulvalene (TTF) analogs have been widely developed in view of increasing the dimensionality of the corresponding conducting materials. [7] However, from a different viewpoint, one can envision taking advantage of the strong p-donor properties of the 1,4-dithiafulvenyl (DTF) group to alter the electronic properties of ex- …”
Section: Methodsmentioning
confidence: 99%
“…[140][141][142][143][144][145][146][147] Of these methods, controlled radical polymerization of vinyl monomers affords a diverse array of methods to prepare new functional surfaces. These include atom transfer radical polymerizations ͑ATRPs͒ from alkyl halides, [148][149][150][151] nitroxide-mediated polymerizations ͑NMPs͒, 151 and reversible addition-fragmentation chain transfer polymerizations from benzyl N , N-diethyldithiocarbamates. 152,153 ATRP is a particularly attractive approach for the preparation of polymer brushes.…”
Section: Fa8 Raynor Et Al: Controlling Cell Adhesion To Biomaterialsmentioning
confidence: 99%
“…[15][16][17][18] During electron irradiation, carbon-hydrogen bonds are cleaved initially, followed by formation of carbon-carbon crosslinks between the aromatic units. Near-edge X-ray absorption fine structure spectroscopy (NEXAFS) [15,19,20] and infrared reflection absorption spectroscopy (IRRAS) [16] both indicate lower molecular order and reduced aromaticity of the crosslinked films.Other examples of crosslinked monolayers that have been previously reported include polymeric SAMs containing polydiacetylene units [21] and polymerized Langmuir-Blodgett films.[22] SAMs containing only aliphatic chains, such as alkanethiols on gold, are not crosslinked by electron irradiation but undergo C-C-and C-H-bond cleavage and desorption at low electron doses.[23]We now show that crosslinked aromatic SAMs can be released from the substrate by selective cleavage of the anchorgroup-substrate bond or by dissolution of the substrate. SAMs of 1,1′-biphenyl-4-thiol (Ia, see Fig.…”
mentioning
confidence: 99%