Polymeric DABCO‐Bromine Complex: A Mild Oxidant for the Preparation of Ketones and Aldehydes.

Struss, John A.; Barnhart, William D.; Velasco, Maria R.; Bronley-DeLancey, Apryl

doi:10.1002/chin.200652049

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“…The polymeric DABCO−bromine complex was used to convert primary and secondary alcohols to the corresponding aldehydes and ketones. 1636 The reaction was carried out in a biphasic system consisting of dichloromethane and water at room temperature. A variety of 1,2-diols were selectively oxidized to their corresponding 1,2-diketones with bromamine-T using RuCl 3 •xH 2 O as the catalyst in an alkaline mixture of acetonitrile and water in a 1:1 ratio.…”

Section: Oxidation Reactions Using Other Bromo-organic Compoundsmentioning

confidence: 99%

Use of Bromine and Bromo-Organic Compounds in Organic Synthesis

2016

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Bromination is one of the most important transformations in organic synthesis and can be carried out using bromine and many other bromo compounds. Use of molecular bromine in organic synthesis is well-known. However, due to the hazardous nature of bromine, enormous growth has been witnessed in the past several decades for the development of solid bromine carriers. This review outlines the use of bromine and different bromo-organic compounds in organic synthesis. The applications of bromine, a total of 107 bromo-organic compounds, 11 other brominating agents, and a few natural bromine sources were incorporated. The scope of these reagents for various organic transformations such as bromination, cohalogenation, oxidation, cyclization, ring-opening reactions, substitution, rearrangement, hydrolysis, catalysis, etc. has been described briefly to highlight important aspects of the bromo-organic compounds in organic synthesis.

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Section: Oxidation Reactions Using Other Bromo-organic Compoundsmentioning

confidence: 99%