2008
DOI: 10.1002/adfm.200701073
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Polydisperse Aggregates of ZnO Nanocrystallites: A Method for Energy‐Conversion‐Efficiency Enhancement in Dye‐Sensitized Solar Cells

Abstract: ZnO films consisting of either polydisperse or monodisperse aggregates of nanocrystallites were fabricated and studied as dye‐sensitized solar‐cell electrodes. The results revealed that the overall energy‐conversion efficiency of the cells could be significantly affected by either the average size or the size distribution of the ZnO aggregates. The highest overall energy‐conversion efficiency of ∼4.4% was achieved with the film formed by polydisperse ZnO aggregates with a broad size distribution from 120 to 36… Show more

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Cited by 286 publications
(207 citation statements)
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References 35 publications
(30 reference statements)
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“…It can be synthesized by solution-based or vapor-based methods into various types of nano-structures, ranging from nanoparticles [17,22] over nanorods, [19,23] nanorings, [24] tetrapods, [25] to nanowires. [23,26] We have used a mono-disperse core-shell system with a spherical ZnO core with a diameter of about 5 nm coated with an organic ligand shell of about 1 nm thickness.…”
mentioning
confidence: 99%
“…It can be synthesized by solution-based or vapor-based methods into various types of nano-structures, ranging from nanoparticles [17,22] over nanorods, [19,23] nanorings, [24] tetrapods, [25] to nanowires. [23,26] We have used a mono-disperse core-shell system with a spherical ZnO core with a diameter of about 5 nm coated with an organic ligand shell of about 1 nm thickness.…”
mentioning
confidence: 99%
“…9c). The enhanced absorption of the ZnO-CNT fiber composite may have been due to chemical bonds between the Zn and carbon [41], oxygen vacancy defects in the presence of the Zn d-d transition [36], carbon doping of the ZnO nanoparticles [42], or multiple light scattering [43] by the ZnO nanospheres (as shown in Fig. 2).…”
Section: Resultsmentioning
confidence: 99%
“…Lightscattering centers are formed by submicrometer-sized particles added to a nanocrystalline film. [9][10][11] Some other nanostructures such as nanowires and nanotubes have also been attempted.…”
Section: )mentioning
confidence: 99%