Articles you may be interested inEffects of fluorine incorporation and forming gas annealing on high-k gated germanium metal-oxidesemiconductor with Ge O 2 surface passivation Appl. Phys. Lett. 93, 073504 (2008); 10.1063/1.2966367 On the dc and noise properties of the gate current in epitaxial Ge p -channel metal oxide semiconductor field effect transistors with Ti N ∕ Ta N ∕ Hf O 2 ∕ Si O 2 gate stack Investigation of etching properties of metal nitride/high-k gate stacks using inductively coupled plasma J. Vac. Sci. Technol. A 23, 964 (2005); 10.1116/1.1927536Physical and electrical properties of metal gate electrodes on HfO 2 gate dielectrics Reduced etching rates of advanced metal gates ͑TaN, TiN, and HfN͒ using SiO 2 /Si 3 N 4 hard masks are observed in Cl 2 plasma. Si and O released from hard masks react with metal surfaces newly exposed to the plasma during the etching, thereby forming metal oxides. The metal oxides formed on the etched surface retard the etch rates. The suppression of etch rates with hard mask is more obvious for TiN than for TaN and HfN, because Ti oxides are readily formed on the etched TiN surface due to their low Gibbs free energies of formation. The surface of TiN degrades with etching time with SiO 2 mask, because etching rates of Si oxides and Ti oxides are different in the ͑TiO 2 ͒ 1−x ͑SiO 2 ͒ x residues remaining on the etched surface. In contrast, a conventional poly-Si electrode does not show the mask effects on etch rates and surface roughness.