Organic solutions of lithium pentafluorobenzene sulfonate (C 6 F 5 SO 3 Li) with varying molalities in N,Ndimethyl formamide (DMF) and triethyleneglycol dimethylether (triglyme) were investigated by Raman spectroscopy. Spectral decomposition in the n s (SO 3 ) stretching region showed bands characteristic of free anions, ion pairs and various aggregates. The relative fraction of each species has been followed as a function of salt molality. In DMF, free anions dominate, while in triglyme ion pairs dominate, in accordance with the solvent dielectric constant.