New glyme–cyclic imide lithium salt complexes as thermally stable electrolytes for lithium batteries

Excellent Compatibility of Solvate Ionic Liquids with Sulfide Solid Electrolytes: Toward Favorable Ionic Contacts in Bulk‐Type All‐Solid‐State Lithium‐Ion Batteries

“…At this composition, unique room temperature ionic liquid (RTIL)-like behaviors were observed. [34][35][36] The SILs such as Li(glyme) y X (X: polyanion) [ 33 ] and Li(acetonitrile (AN)) 2 [bis(trifl uoromethanesulfonyl)imide (TFSI)] [ 31 ] have been shown to suppress the dissolution of lithium polysulfi des, resulting in excellent performance in Li-S batteries. In addition, the superior safety properties (nonfl ammability, low volatility, and excellent thermal stability) of ionic liquids compared to the conventional LEs should be noted.…”

The interface between HOPG and 1-butyl-3-methyl-imidazolium hexafluorophosphate

“…From an electrochemical point of view, their most promising field of application is the design of energy-storage devices such as batteries and supercapacitors. 5,6,7 In addition, ionic liquids (especially the air-and water-stable imidazolium-based ones 8 ) can also be used as electrolytic media for the electrodeposition of highly reactive materials 9,10 . In order to facilitate these applications, a general understanding of the physical chemistry of metal | IL in-2 terfaces is required; this is the reason why ionic liquids are in the focus of a continuously growing interest in both experimental and theoretical research.…”

AlCl3-dissolved Diglyme as Electrolyte for Room-Temperature Aluminum Electrodeposition

“…glymes receive attention as relatively safe solvents for lithium and magnesium ion batteries, because they have high boiling points above 150°C and relatively low volatilities at RT in addition to their good chelating ability. [23][24][25][26] Furthermore, previous NMR studies have indicated sizable amount of ionic Al species in glyme solutions, 27 possibly giving good conductivities. To the best of our knowledge, however, there have been no reports on their electrochemical properties.…”