Polarographic Oxidation of Phenolic Compounds

Gaylor, V. F.; Elving, Philip J.; Conrad, A. L.

doi:10.1021/ac60079a022

Cited by 64 publications

(28 citation statements)

References 13 publications

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“…doi:10.1016/j.jelechem.2008.11.004 reaction and enhancing the sensitivity and selectivity of the detection method [18]. Electrochemical methods have been used successfully in the detection of some phenolic compounds since most of phenols can be oxidized at readily accessible potentials [19,20]. It is well known that cobalt phthalocyanine complexes can effectively catalyze the electrooxidation of organic compounds for the function of redox mediators.…”

Section: Introductionmentioning

confidence: 99%

Preparation and characteristic of cobalt phthalocyanine modified carbon paste electrode for bisphenol A detection

Yin

Zhou

2009

Journal of Electroanalytical Chemistry

150

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Section: Introductionmentioning

confidence: 99%

Preparation and characteristic of cobalt phthalocyanine modified carbon paste electrode for bisphenol A detection

Yin

Zhou

2009

Journal of Electroanalytical Chemistry

150

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“…These two compounds actually have been obtained from phenol by electrolytic oxidation and by oxidation with peroxysulfuric acid. Because these dihydroxy compounds are oxidized even more easily than phenol itself, the oxidation generally proceeds further and yields other products (9). The relative difficulty of oxidizing phenol is apparent from the markedly lower anode potential of this compound as compared with the potentials of the di-and tri-hydroxybenzene compounds.…”

Section: Experimental Data and Discussion Of Resultsmentioning

confidence: 99%

“…The curve has a slope of --0.058 in close agreement with the theoretical value of --0.0591. The half-wave potential of hydroquinone also has been found to decrease linearly with increasing pH in the range of pH 1 to 8 (9).…”

Section: Nh~ Nhmentioning

confidence: 93%

Investigation of the Electrochemical Characteristics of Organic Compounds

Glicksman

1961

J. Electrochem. Soc.

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A study of the electrochemical characteristics of aromatic hydroxy, aromatic amine, and aminophenol compounds in basic electrolyte shows that the anode potential of these compounds depends on the aromaticity of the compound, as well as the type and position of substituted groups on the aromatic ring. The effect of these factors on the anode potential is interpreted in terms of the electron density distribution in the molecule. The use of these compounds as anode materials in primary cells also is considered.

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“…Only minor discrepancies can be found for formation of CH 2 Cl 2 and destruction of CH 2 Cl between the complex and reduced kinetic models. Figure 6.2 shows the destruction of CH 2 Cl. The reduced model takes a slightly small time for destruction of CH 2 Cl, but the agreement is still good.…”

Section: Validation Of the Reduced Mechanismmentioning

confidence: 99%

Decontamination Systems Information and Reseach Program

Cook¹

1998

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The following paragraphs comprise the research efforts during the first quarter of 1998 (January 1 -March 31). These tasks have been granted a continuation from the 1997 work and will all end in Progress was also marked on the Injection and Circulation of Potable Water Through PVDs task. Data reduction from this sequence of testing is ongoing. Work planned for next quarter includes completing the Injection / Extraction of potable water task and beginning the Surfactant Injection and removal task. Work by The Institute of Gas Technology (IGT) this quarter on Task 1.7 -Technical Support for Surfactantconsists of continuing with the field work initiated in 1997 on the field pilot study on the use of PVDs enhanced with a surfactant flushing solution for removal of TCE from contaminated fine-grain fraction soil and groundwater.iii

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Polarographic Oxidation of Phenolic Compounds

Cited by 64 publications

References 13 publications

Preparation and characteristic of cobalt phthalocyanine modified carbon paste electrode for bisphenol A detection

Preparation and characteristic of cobalt phthalocyanine modified carbon paste electrode for bisphenol A detection

Investigation of the Electrochemical Characteristics of Organic Compounds

Decontamination Systems Information and Reseach Program

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