Polarization of cyanogen(B2.SIGMA.+-X2.SIGMA.+) emission produced in collision of argon(3P0,2) with bromine cyanide (BrCN)

Production of CN(B2Σ+) state from dissociative excitation reaction of BrCN with microwave discharge flow of Ar

“…Extensive studies have been made for this transition to determine the molecular parameters and to elucidate electronic structures of relevant electronic states [1][2][3][4][5][6][7][8][9]. This emission has been also studied to make the dynamical analysis of the dissociation process [10][11][12][13][14][15][16], where particular emphasis has been put on the energy-transfer collision with metastable states of Ar, Ar( 3 P 0,2 ), Ar( 3 P 0;2 ) + BrCN ! Ar + Br + CN(B 2 R þ ).…”