This study combines simulation and experiment to compare the impact that changing BARC thickness around some nominal value has on the resist profile, on an underlying reflective surface. Process window and profile effects are an important part of understanding how a BARC interacts with the resist's parameters to affect the latitude in the light of imperfect reflection control. Reflectivity simulations are made using MATLAB ® and Prolith™ that show the effect of choosing refractive index and thickness in a multi-layer bottom anti-reflecting coating (BARC). Trends are identified for the better operating values for the index as well as specific values that meet the criterion for organic BARC in a front end application on a reflective substrate. Experimental profiles are compared to simulation using a calibrated resist model for nominal, better and ideal BARC stacks. Reflectivity, as a function of angle in resist, is convolved with the diffraction intensity distribution. This reflection, determined by a pitch's diffraction angle, identifies what can become problematic in setting up a process. Depolarization causes are discussed and while their impact affects image formation, there is little difference in reflection.
II. INTRODUCTIONPrinting features near the resolution limit of hyper-NA exposure systems has many challenges, one of which is reflection control. The angle at which light rays pass through the absorbing films of the stack is dependent upon the mask pitch. This effect becomes limiting below 65 nm half-pitch for single BARC layers because reflectivity varies significantly with pitch. At the same time, resist thickness is scaled thinner; therefore the BARC needs to become even thinner. Increasing the BARC index (n BARC ) has been shown to decrease its required thickness, but limiting reflection to very low values for all pitches cannot be done with a single BARC film.(1) Prior work has demonstrated dual BARCs provide lower reflection down to 1%.(2) Below that, additional strategies are needed for low light reflection through pitch. This work extends the effort on reducing reflectivity to below 0.2% while also keeping the BARC thickness to below that expected for the resist.Reflectivity plays a role in resist profile as a function of focus and exposure and hence, process latitude. Estimates for the maximum allowable reflectivity on a flat substrate ranges from 0.5% to less than 0.1% across any portion of the lens. (3) While the physical resist parameters, especially photoacid diffusivity(4), also directly impact the standing wave amplitude seen on the sidewall and interface of the profile, the main thrust of this work is the examination of optical reflectivity effects.
IIa. Reflectivity and PitchThe angle of any light ray, and thus its position in the pupil plane, is determined by the angle at which it diffracts through the mask. For the zero order and m th order the angle is: θ 0 (deg) ≈ (180/π)sin -1 (σNA/n) θ m (deg) ≈ θ 0 +(180/π)sin -1 (mλ/pitch) , m = +1 at resolution limit Downloaded From: http://proce...