Some characteristics of the picosecond laser produced plasma expanding across an externally applied magnetic field (0.6 T) have been reported. Two to three times enhancement in X-ray emission from copper plasma has been observed for the laser intensity range ~5 X 10" to 5 X 10 12 W/cm 2 . The X-ray yield has been found to increase with an increase in the magnetic field intensity. Enhancement in X-ray emission is correlated with confinement of expanding plasma either in external magnetic field or in high ambient gas pressure. Generation of some highfrequency instability and fast ions was also observed in the plasma along with bouncing of plasma near the ft = 1 surface where kinetic pressure of plasma equals magnetic pressure.