“…An emission feature around 1.95 eV was observed for both Cu 2 O microcrystals and the natural bulk sample, which has been reported repeatedly in literature. It was attributed to phononassisted transitions and defect emission in close spectral proximity 14,27,28 with the latter potentially being correlated with local strain in the sample 29 . The ratio of excitonic over defect emission for the measurements shown in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…Apart from quantum optics, recent reports have reinforced the significant potential of Cu 2 O as a lowcost, non-toxic material in areas such as photocatalysis 8 , solar water splitting 9 , and solar cell devices 10 showing promising photovoltaic efficiencies and marked excitonic effects 11 . Various methods have been reported for the growth of Cu 2 O thin films and single crystals 12 , in particular molecular beam epitaxy 13,14 , magnetron sputtering 15,16 in combination with thermal annealing 17 , electrodeposition 18 , thermal oxidation 19 , and the floating zone method 20 . However, state-of-the-art quantum optics experiments still focus on natural bulk crystals originating from mines, clearly underlining that significant progress in Cu 2 O growth is required to surpass inherent limitations of natural samples.…”
Cuprous oxide (Cu 2 O) is a semiconductor with large exciton binding energy and significant technological importance in applications such as photovoltaics and solar water splitting. It is also a superior material system for quantum optics that enabled the observation of intriguing phenomena, such as Rydberg excitons as solid-state analogue to highly-excited atomic states. Previous experiments related to excitonic properties focused on natural bulk crystals due to major difficulties in growing high-quality synthetic samples. Here, the growth of Cu 2 O microcrystals with excellent optical material quality and very low point defect levels is presented. A scalable thermal oxidation process is used that is ideally suited for integration on silicon, demonstrated by on-chip waveguide-coupled Cu 2 O microcrystals. Moreover, Rydberg excitons in site-controlled Cu 2 O microstructures are shown, relevant for applications in quantum photonics. This work paves the way for the wide-spread use of Cu 2 O in optoelectronics and for the development of novel device technologies.
“…An emission feature around 1.95 eV was observed for both Cu 2 O microcrystals and the natural bulk sample, which has been reported repeatedly in literature. It was attributed to phononassisted transitions and defect emission in close spectral proximity 14,27,28 with the latter potentially being correlated with local strain in the sample 29 . The ratio of excitonic over defect emission for the measurements shown in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…Apart from quantum optics, recent reports have reinforced the significant potential of Cu 2 O as a lowcost, non-toxic material in areas such as photocatalysis 8 , solar water splitting 9 , and solar cell devices 10 showing promising photovoltaic efficiencies and marked excitonic effects 11 . Various methods have been reported for the growth of Cu 2 O thin films and single crystals 12 , in particular molecular beam epitaxy 13,14 , magnetron sputtering 15,16 in combination with thermal annealing 17 , electrodeposition 18 , thermal oxidation 19 , and the floating zone method 20 . However, state-of-the-art quantum optics experiments still focus on natural bulk crystals originating from mines, clearly underlining that significant progress in Cu 2 O growth is required to surpass inherent limitations of natural samples.…”
Cuprous oxide (Cu 2 O) is a semiconductor with large exciton binding energy and significant technological importance in applications such as photovoltaics and solar water splitting. It is also a superior material system for quantum optics that enabled the observation of intriguing phenomena, such as Rydberg excitons as solid-state analogue to highly-excited atomic states. Previous experiments related to excitonic properties focused on natural bulk crystals due to major difficulties in growing high-quality synthetic samples. Here, the growth of Cu 2 O microcrystals with excellent optical material quality and very low point defect levels is presented. A scalable thermal oxidation process is used that is ideally suited for integration on silicon, demonstrated by on-chip waveguide-coupled Cu 2 O microcrystals. Moreover, Rydberg excitons in site-controlled Cu 2 O microstructures are shown, relevant for applications in quantum photonics. This work paves the way for the wide-spread use of Cu 2 O in optoelectronics and for the development of novel device technologies.
“…The growth of Te film could be controlled by pulse parameters. In MBE technology, 72 the vapor obtained by heating in an ultrahigh vacuum is directly sprayed onto the substrate, so that the atoms are arranged on the substrate according to the crystal to form a thin film. The use of MBE in the synthesis of tellurene has also been confirmed.…”
Section: Synthesis Of 2d Tellurene Nanomaterialsmentioning
Tellurium nanomaterials show unique advantages, including high carrier mobility, excellent optical properties, and high specific surface areas. Although previous studies have confirmed the application of tellurium nanomaterials in the biological...
“…Отметим, что в последние годы активно развиваются новые технологии получения тонких, в том числе эпитаксиальных слоев и нанонитей Cu 2 O (см, например, [16][17][18]).…”
The low-temperature luminescence spectra of Cu2O crystals grown by the different methods (copper oxidation, induction melting, magnetron sputtering, hydrothermal synthesis) and of natural crystal are compared. It was concluded that the high quality of natural crystals and crystals grown by the hydrothermal method is due to the low temperature process of their formation which minimizes the strains.
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