This study reports
flexible nanocomposite-based piezoelectric nanogenerators
(PENGs) fabricated by dispersing various piezoelectric nanoparticles
(BaTiO3, ZnO, and PZT) and graphene nanopowder in a silicone
matrix. The results indicated that the PZT-based composites showed
superior performance in comparison to other ceramics. Subsequently,
practical application of PENGs was demonstrated by developing a fully
functioning shoe-insole nanogenerator (SING). The SING generated high
open-circuit voltage (∼27 V), short-circuit current (429.23
μA), and power density (402 mW/m2) under real-time
human walking. Moreover, a facile and inexpensive fabrication method
for efficient, skin-friendly, and highly stretchable biomechanical
piezoelectric sensors is also proposed. In this regard, multiwall
carbon nanotubes/silicone composite stretchable electrodes were prepared
to be compatible with the sensors. The electrodes displayed stability
even under high uniaxial elongation (100%), and the fabricated sensors
responded effectively to almost every joint movement. The results
suggested that the fabricated PENGs can be potentially used as self-powered
biomechanical energy harvesters/sensors in wearable electronics, haptic
sensing, or internet of human-related applications.