Solubility diagram was investigated by the method of saturation in ampules at 25 ± 0.02 • C for 4 hours. The solubility diagram of the PrCl 3-C 60 (OH) 24-H 2 O ternary system at 25 • C occurs as simple eutonics, consisting of two branches, corresponding to the crystallization of crystalhydrates: PrCl 3 • 7H 2 O and C 60 (OH) 24 • 18H 2 O. The diagram contains one non-variant point each-eutonics, which corresponds to saturation with pair of crystal-hydrates simultaneously. The diagram also contains very short branch of PrCl 3 • 7H 2 O crystallization, and long branch of C 60 (OH) 24 • 18H 2 O, where the effect of fullerenol salt-out is distinctly observed.