Physico-chemical characterization, Hirshfeld surface analysis and opto-electric properties of a new hybrid material: Tris (2-amino-5-chloropyridinium) hexachlorobismuthate(III)

Abstract

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Crystal structure, computational study, optical and vibrational properties of a new luminescent material based on bismuth(III): (C10H28N4)[Bi2Cl10]

“…These Bi-Cl distances, shortest than the sum of the Van der Waals radii of the bismuth and the chlorine atoms 3.82 Å, are in good conformity with data for similar compounds [54][55][56][57].…”

Stabilization of Tetrachloride with Mn (II) and Co (II)Complexes and 4-Tert-Butylpyridinium Organic Cation: Elaboration of the Structure and Hirshfeld Surface, Optical, Spectroscopic and Thermal Analyses

“…A view of the inorganic portion in perspective (Figure 4a,b) shows that the isolated [MCl 4 ] 2− occurs in the (0, 0, 0), (0, 1 2 , 1 4 ), ( 1 2 , 0, 3 4 )and ( 1 2 , 1 2 , 1 2 ) positions. If we look at compound (I), we can see that the [MnCl 4 ] 2tetrahedron is defined by manganese and four chloride atoms (Cl1, Cl1 i , Cl1 ii and Cl1 iii ).…”

“…Among the organic ligands, pyridine is often utilized during synthesis due to the presence of an aromatic nitrogen atom with an unbound electron pair that is ideally positioned to operate in synthetic fragments. Indeed, this atom and its derivatives have been manipulated with several transition metals to produce new materials with different structures and properties [1][2][3]. Transition metal complexes represent a very important area in the field of chemistry due to their coordination properties.…”

One-Dimensional Organic–Inorganic Material (C6H9N2)2BiCl5: From Synthesis to Structural, Spectroscopic, and Electronic Characterizations

“…Halometallates (III) organic-inorganic materials have generated significant interest because of their special structural features and high potential applications, such as electronic and optical materials [ 1 , 2 , 3 , 4 , 5 , 6 ]. Among these classes of materials, halogeno bismuthate(III) with general formula A a B b X 3b+a , where A = organic amine and X = I, Br, Cl, have emerged as an up-and-coming class of luminescent and semiconducting materials and have stimulated considerable interest among researchers [ 7 , 8 , 9 , 10 , 11 , 12 ]. The anion substructure of these materials comprises MX 6 octahedra that may be isolated (zero-dimensional—0D) or linked by edges, corners or faces (1D, 2D, 3D architectures) [ 13 , 14 , 15 ].…”