2009
DOI: 10.1021/je900689m
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Physical Properties of Binary Mixtures of Ethyl Formate with Benzene, Isopropyl Benzene, Isobutyl Benzene, and Butylbenzene at (303.15, 308.15, and 313.15) K

Abstract: Densities, viscosities, and speeds of sound of binary mixtures of ethyl formate with benzene, isopropyl benzene, isobutyl benzene, and butylbenzene have been measured over the entire range of composition, at (303.15, 308.15, and 313.15) K and at atmospheric pressure. The excess volume, V E, deviation in viscosity, Δη, and deviation in isentropic compressibility, ΔK s, have been calculated from the experimental values of density, viscosity, and ultrasonic velocity. The excess volumes are positive, while the dev… Show more

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Cited by 35 publications
(15 citation statements)
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“…Equation for best of density of butylcyclohexane is ρ/kg·m 3 = 1127.02 – [1.46341 × T /K] + [1.17912 × 10 –3 × ( T /K) 2 ]. k Reference . l Reference . m Reference . n Reference . Equation for best of density of toluene is ρ/kg·m 3 = 1.18621 × 10 3 – [1.47573 × T /K] + 2.08566 × 10 –3 × ( T /K) 2 – 2.61945 × 10 –6 ( T /K) 3 . o Reference . p Reference . q Reference . r Reference . s Reference . t Reference . u Reference . v Reference . w References and for error. x Reference . y Reference . z Reference . …”
Section: Resultsmentioning
confidence: 99%
See 2 more Smart Citations
“…Equation for best of density of butylcyclohexane is ρ/kg·m 3 = 1127.02 – [1.46341 × T /K] + [1.17912 × 10 –3 × ( T /K) 2 ]. k Reference . l Reference . m Reference . n Reference . Equation for best of density of toluene is ρ/kg·m 3 = 1.18621 × 10 3 – [1.47573 × T /K] + 2.08566 × 10 –3 × ( T /K) 2 – 2.61945 × 10 –6 ( T /K) 3 . o Reference . p Reference . q Reference . r Reference . s Reference . t Reference . u Reference . v Reference . w References and for error. x Reference . y Reference . z Reference . …”
Section: Resultsmentioning
confidence: 99%
“… a Standard uncertainties u are u ( T ) = 0.01 K, and expanded uncertainties U c are U c ( c ) = 0.8 m·s –1 . The average pressure P for these measurements was 0.102 MPa with an expanded uncertainty U c ( P ) = 0.002 MPa (level of confidence = 0.95, k = 2). b Reference . c Reference . d Reference . e Reference . f Reference . g Reference . h Reference . i Reference . j Reference . k Reference . l Reference . m Reference . n Reference . o Reference . p Reference . q Reference . r Reference . s Reference . t Reference . u Reference . …”
Section: Resultsmentioning
confidence: 99%
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“… a Standard uncertainties u are u ( T ) = 0.01 K, and expanded uncertainties U c are U c (ρ) = 0.07 kg·m –3 for T < 353.15 K and U c (ρ) = 0.2 kg·m –3 for T ≥ 353.15 K (level of confidence = 0.95, k = 2). The average pressure for these measurements was 0.102 MPa with an expanded uncertainty U c ( P ) = 0.001 MPa (level of confidence = 0.95, k = 2). b Reference . c Reference . d Reference . Equations for best density: Decane: ρ/kg·m 3 = 999.915 – [1.25380 × T /K] + [1.72986 × 10 –3 ( T /K) 2 ] – [2.02727 × 10 –6 ( T /K) 3 ]. Dodecane: ρ/kg·m 3 = 1046.13 – [1.49513 × T /K] + [2.35839 × 10 –3 ( T /K) 2 ] – [2.43796 × 10 –6 ( T /K) 3 ]. Tetradecane: ρ/kg·m 3 = 1093.4 – [1.73979 × T /K] + [2.82238 × 10 –3 ( T /K) 2 ] – [2.49190 × 10 –6 ( T /K) 3 ]. Hexadecane: ρ/kg·m 3 = 956.848 – [0.557634× T /K] + [2.68578 × 10 –4 ( T /K) 2 ] – [1.24436 × 10 –7 ( T /K) 3 ]. Heptadecane: ρ/kg·m 3 = 1026.08 – [1.11241 × T /K] + [1.28506 × 10 –3 ( T /K) 2 ] – [1.28491× 10 –6 ( T /K) 3 ]. e Reference . f Reference . g Reference . h Reference . i Reference . j Reference . k Reference . l Reference . m Reference . …”
Section: Resultsmentioning
confidence: 99%
“… a Standard uncertainties u are u ( T ) = 0.01 K, and expanded uncertainties U c are U c ( c ) = 0.5 m·s –1 (level of confidence = 0.95, k = 2) unless otherwise indicated by “±” symbol. The average pressure for these measurements was 0.102 MPa with an expanded uncertainty U c ( P ) = 0.001 MPa (level of confidence = 0.95, k = 2). b Reference . c Reference . d Reference . e Reference . f Reference . g Reference . h Reference . i Reference . j Reference . k Reference . l Reference . m Reference . n Reference . o Reference . p Reference . q Reference . …”
Section: Resultsmentioning
confidence: 99%