Phy-chemical Attributes of Nano-scale V2O5/TiO2 Catalyst and Its’ Effect on Soot Oxidation

Abstract

The V2O5 catalysts which supported on nano-scale TiO2 with variation of vanadium contents (5%, 10%, 20% and 40%) were prepared by an incipient-wetness impregnation method. The phase structures of nano-scale V2O5/TiO2 catalysts with different loading rates were characterized by Scanning electron microscope (SEM), X-Ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectra. The oxidation activities of catalysts over diesel soot were performed in a themogravimetric analysis (TGA) system. The kinetics of the catalytic oxidation process were analyzed based on Flynn-Wall-Ozawa method. The characterization results showed that the phase structure of V2O5 supported on TiO2 depends heavily on the vanadium contents, which will put great effects on the catalytic performances for soot oxidation. At a low vanadium loading rates (V5-V20), active species exist as monomers and polymeric states. At a high loading rate (V40), the crystalline bulk V2O5 covers the surface of TiO2. The formed crystal structure occupied the active sites and led a decreasing in the catalytic effect. By comparing the characteristics temperatures of soot oxidation over V2O5 catalysts, the catalytic activities of catalysts with different loading rates for soot oxidation can be ranked as: V5 < V10 < V40 < V20. Via pyrolysis kinetics analysis, it is revealed that the activation energy of soot oxidation is minimum when the vanadium loading rates is 20%, which is fit well with the TG experimental results. The consistency of pyrolysis kinetics and TG experimental results confirm that the best activity catalyst is V20 in discussed catalysts of this paper, which is nearest to the monolayer dispersion saturated state of V2O5/TiO2 catalyst. Moreover, it convincingly demonstrate the obvious threshold effect in V2O5 catalysts.

Fabrication of TiVO4 photoelectrode for photoelectrochemical application

“…23,31 Numerous pioneering reports highlighted the superior performance of TiV systems as composites VO x /TiO 2 or as doping compared to TiVO 4bimetal oxide on their plausible photocatalysis application. 32,33 Samdarshi et al (2010) evaluated the effect of silver on the titanium vanadium mixed metal (Ag/ TiV) oxides. 34 They observed that the system could absorb a large portion of the visible spectrum, where favourable electron transfer could be experienced anatase-rutile mixed phase where silver dominated through its scavenging action to reduce hole recombination.…”

Preface of BCREC Volume 11 Issue 2 Year 2016

“…The addition of ZrO2 into TiO2 is able to increase the photocatalytic activity proven by 88.75 % degradation of MB at a ZrO2-TiO2 weight ratio of 1:1. Meanwhile, the V2O5 catalysts which supported on nano-scale TiO2 with variation of vanadium contents (5%, 10%, 20% and 40%) were studied by Mei et al [6]. The characterization results showed that the phase structure of V2O5 supported on TiO2 depends heavily on the vanadium contents, which will put great effects on the catalytic performances for soot oxidation.…”

“…Another article focused on TiO2-based catalysts were conducted by Permadani et al [5] and Mei et al [6]. The composite of ZrO2-TiO2 produced from local zircon sand as a photocatalyst for the degradation of methylene blue in a single batik dye wastewater was studied by Permadani et al [5].…”