The optical damage behaviour of different LiNbO 3 optical waveguides has been experimentally studied by measuring the intensity output of a single beam as a function of the intensity input. Parallel measurements of photovoltaic currents have been carried out as a function of the input intensity and they have been correlated with the optical damage data. The following LiNbO 3 guides have been studied and compared: proton exchanged (PE) belonging to the phases α, β 1 , β 2 and reverse proton exchanged (RPE) and Zn in-diffused waveguides. The greatest intensity thresholds for optical damage, about 2x10 3 times greater than that of the substrate, have been obtained in RPE guides (they support ordinary polarization and have similar nonlinear optic activity as the substrate) and β 2 guides which support extraordinary polarization (they have no nonlinear optic activity). On the other hand, the lowest photovoltaic currents have been measured in β 1,2 -phases. As a function of the light intensity, the photovoltaic current exhibits a superlinear behaviour, strong in α-phase and weaker in Zn in-diffused and RPE guides. The results for optical damage are discussed in connection with those of photovoltaic currents, paying particular attention to the main mechanisms involved.