Photometrische Bestimmung der freien Bildungsenthalpie wässerigen Nitrosylchlorids

Schmid, Hermann; Maschka, Α.

doi:10.1515/zpch-1941-4917

Cited by 17 publications

(4 citation statements)

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“…Thus, with silver perchlorate it yields silver chloride and nitrosyl perchlorate; with silver nitrate, nitrogen dioxide (298, 307). Hydrolysis or alcoholysis yields hydrochloric acid and (respectively) nitrous acid or an alkyl nitrite (226,356). In addition to unsaturated compounds on the other hand, primary homolysis to NO and Cl offers as adequate an explanation as does primary homolysis to 2N02 by N204.…”

Section: Analogous Systemsmentioning

confidence: 99%

The Reactivity And Structure Of Nitrogen Dioxide

Gray¹,

Yoffe²

1955

Chem. Rev.

130

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Section: Analogous Systemsmentioning

confidence: 99%

The Reactivity And Structure Of Nitrogen Dioxide

Gray¹,

Yoffe²

1955

Chem. Rev.

130

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“…NOCl(aq) + H20(1) -> HN02(aq) + HCl(aq) photometric means being used for measuring the concentration of nitrosyl chloride (428).…”

Section: Physical Propertiesmentioning

confidence: 99%

“…The equilibrium constant at 25°C. has been measured (428) for the reaction in dilute aqueous solution:…”

Section: B Photochemical Dissociationmentioning

confidence: 99%

Nitrosyl Chloride.

Beckham¹,

Fessler²,

Kise³

1951

Chem. Rev.

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“…Here, it is intended tocombine kineticdataon thechloride-catalyseddiazotisation of aniline and p-toluidine, with equilibrium data on the hydrolysis of nitrosyl chloride [4], and on the proton ionisation of the anilinium [5,6] and p-toluidinium [7] ions; to calculate the specific reaction rate, AG*, A H * , AS*, and E, for the rate-determining stage; and to compare these values with those for p-chloroaniline [8].…”

mentioning

confidence: 99%

The Influence of Certain Nuclear p‐Substituents on the Kinetics of N‐Nitrosation and Diazotisation of Aniline

Aboul‐Seoud

Ahmad²

1969

Bulletin des Soc Chimique

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The specific reaction rates for the chloride-catalysed diazotisation of aniline and p-toluidine were combined with equilibrium data on the proton ionisation of the anilinium and p-toluidinium ions, and on the hydrolysis of nitrosyl chloride. The specific reaction rates were calculated for the N-nitrosation of the free amines, which is the rate-determining stage in the diazotisation of the amines, under the present conditions. A G * , A H * , A S * , and E were determined for this rate-determining stage. These values were compared with the corresponding values for p-chloroaniline. The influence of the substituents on the rates of the N-nitrosation of these amines was discussed.

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Photometrische Bestimmung der freien Bildungsenthalpie wässerigen Nitrosylchlorids

Cited by 17 publications

References 0 publications

The Reactivity And Structure Of Nitrogen Dioxide

The Reactivity And Structure Of Nitrogen Dioxide

Nitrosyl Chloride.

The Influence of Certain Nuclear p‐Substituents on the Kinetics of N‐Nitrosation and Diazotisation of Aniline

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