2002
DOI: 10.1063/1.1464661
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Photomagnetism and structure in cobalt ferrite nanoparticles

Abstract: Light-induced changes in the coercivity ΔHc are reported for cobalt ferrite nanoparticles. These changes arise from charge transfer initiated by optical absorption near 2 eV. An insulator-to-metal transition at 170 K is an upper limit for significant ΔHc. The larger ΔHc for smaller (17 nm) particles was correlated with a distortion about the Co2+ ions at B sites, which increases the absorption probability.

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Cited by 164 publications
(97 citation statements)
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“…are currently used as key materials for the advancements in information storage systems, ferrofluid technology, magnetic refrigeration, detoxification of biological fluids, magnetic resonance imaging (MRI) contrast enhancement, and magnetic cell separation. 1,2 Nanoparticles of magnesium ferrite (MgFe 2 O 4 ) are the potential candidate for various applications due to their high electrical resistivity, low magnetic and dielectric losses. 3,4 These applications include usage in microwave control components and electronic device components such as high frequency (HF) antenna design, transformers, etc.…”
Section: Introductionmentioning
confidence: 99%
“…are currently used as key materials for the advancements in information storage systems, ferrofluid technology, magnetic refrigeration, detoxification of biological fluids, magnetic resonance imaging (MRI) contrast enhancement, and magnetic cell separation. 1,2 Nanoparticles of magnesium ferrite (MgFe 2 O 4 ) are the potential candidate for various applications due to their high electrical resistivity, low magnetic and dielectric losses. 3,4 These applications include usage in microwave control components and electronic device components such as high frequency (HF) antenna design, transformers, etc.…”
Section: Introductionmentioning
confidence: 99%
“…Due to exceptional magnetoelastic, magnetotransport, magnetooptical, photomagnetic, electronic, and magnetic properties, cobalt ferrite ͑CFO͒ has been proposed for applications in noncontact force and torque sensors, 1 as spin filters for magnetic tunnel junctions, 2 for hybrid data storage, 3 for magnetooptical media, 4 and as anode materials for advanced Li-ion batteries. 5 Depending on the requirements of application, magnetic and magnetoelastic properties of CFO can be fine-tuned by appropriate cation substitution 1,[6][7][8] and magnetic annealing.…”
Section: Introductionmentioning
confidence: 99%
“…For example, photomagnetism in nanoparticles of cobalt ferrite have been related to this type of cation distribution. 1 Its higher magnetocrystalline anisotropy and stronger magnetomechanical effects compared to other spinel ferrites are due to the orbital angular momentum of Co 2þ not being completely quenched by the crystalline field. Consequently, Co 2þ on the octahedral sites of the crystal lattice contributes an orbital moment, comparable to the spin moment, resulting in strong spin-orbit coupling which is responsible for the characteristic properties of cobalt ferrite.…”
mentioning
confidence: 99%