“…2c. About threefold slight thermal quenching of PL intensity observed for SN3 should not be surprising in comparison to the many orders of magnitude thermal quenching of pure a-Si:H [23], taking into account the substantially different E 0 ( % 310 meV) of SN3 and that ( % 60 meV) of a-Si:H. Two main results are that the PL peak wavelength blueshifts and the PL FWHM (DE PL ) broadens with increasing r. Keeping in mind the direct proportionality between r and E 04 (Fig. 1d), the blueshift of the PL band is plotted with respect to E 04 in Fig.…”
“…2c. About threefold slight thermal quenching of PL intensity observed for SN3 should not be surprising in comparison to the many orders of magnitude thermal quenching of pure a-Si:H [23], taking into account the substantially different E 0 ( % 310 meV) of SN3 and that ( % 60 meV) of a-Si:H. Two main results are that the PL peak wavelength blueshifts and the PL FWHM (DE PL ) broadens with increasing r. Keeping in mind the direct proportionality between r and E 04 (Fig. 1d), the blueshift of the PL band is plotted with respect to E 04 in Fig.…”
“…Thus, we can deal with the NBE PL behavior by a tailstate luminescence model for the study of amorphous semiconductor. According to Street [14] and Austin et al [15], the tailstate luminescence can be semi-empirically fitted by…”
“…The shallow n-donor levels and the deeper p-acceptor levels are located within the initial band-gap (1.1 eV width) near to the band tails, which should narrow the gap, as observed. However, the luminescence peak of the a-Si:N:H compound moves to higher energy with increasing nitrogen concentration [446]. The broadened band-gap through nitridation could not be explained in terms of the traditional donor effect, though the nitrogen addition is always believed as n-type doping.…”
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