Photoelectrocatalysis (PEC) has shown
great advantages in sustainable
organic synthesis and wastewater treatment because the PEC process
can minimize electron–hole recombination, thereby improving
the photocatalytic performance. Here, we report a convenient procedure
for preparing immobilized BiOX–TiO2 photoelectrocatalytic
electrodes from a titanium–oxo compound (TOC)-modified carbon
fiber cloth (CFC). Crystalline TOCs composed of Ti12 cations
and bismuth halide anions, [Ti12O14(O
i
Pr)18][Bi3Br11(THF)2] (1) and [Ti12O14(O
i
Pr)18][Bi4I14(THF)2] (2), were grown on CFC. Taking advantage
of the easy hydrolysis of the titanium–oxo cation and bismuth
halide anion, we could easily transform these CFC-immobilized crystals
into BiOX–TiO2/CFC (X = Br or I) photocatalysts,
which facilitates recycling of the catalysts. The photocatalytic dye
degradation test showed that the efficiency did not decrease obviously
after 10 photocatalytic cycles. Using BiOX–TiO2-modified
CFC as electrodes, electrocatalysis (EC), photocatalysis (PC), and
PEC were examined. PEC showed an attractive synergistic effect of
EC and PC. These TOC-modified CFCs would be potential candidates for
catalytic electrodes for sustainable wastewater purification.