Photocatalytic decolorization and mineralization of malachite green in an aqueous suspension of titanium(IV) oxide nano-particles under aerated conditions: correlation between some physical properties and their photocatalytic activity
Abstract:Titanium(IV) oxide (TiO 2 ) nano-particles with various physical properties, which had been prepared by hydrothermal crystallization in organic media (HyCOM) and post-calcination, were used for photocatalytic decomposition of malachite green (MG)
“…Many treatment technologies have been applied to decolorize MG from aqueous medium, such as biodegradation and decolorization Levin et al 2004;Ren et al 2006;Eichlerová et al 2006;Daneshvar et al 2007a, b;Ayed et al 2008;Ali et al 2009;Wu et al 2009;Cheriaa and Bakhrouf 2009;Ayed et al 2010;Du et al 2011;Khataee et al 2011a, b;Shedbalkar and Jadhav 2011;Hu et al 2011;Abd-El-Kareem and Taha 2012); photocatalytic degradation (Hasnat et al 2003;Kominami et al 2003;Lv et al 2005;Yang et al 2005;Chen et al 2007;Sayılkan et al 2007aSayılkan et al , b, 2008Tayade et al 2007;Wang et al 2008a;Ju et al 2008;Asiltürk et al 2009;Prado and Costa 2009;Bansal et al 2009;Kaneva et al 2010;Liu et al 2010;Bojinova and Dushkin 2011; Maximum wavelength 618 nm Table 2 Applications and toxicity of Malachite green dye…”
Adsorption can be efficiently employed for the removal of various toxic dyes from water and wastewater. In this article, the authors reviewed variety of adsorbents used by various researchers for the removal of malachite green (MG) dye from an aqueous environment. The main motto of this review article was to assemble the scattered available information of adsorbents used for the removal of MG to enlighten their wide potential. In addition to this, various optimal experimental conditions (solution pH, equilibrium contact time, amount of adsorbent and temperature) as well as adsorption isotherms, kinetics and thermodynamics data of different adsorbents towards MG were also analyzed and tabulated. Finally, it was concluded that the agricultural solid wastes and biosorbents such as biopolymers and biomass adsorbents have demonstrated outstanding adsorption capabilities for removal of MG dye.
“…Many treatment technologies have been applied to decolorize MG from aqueous medium, such as biodegradation and decolorization Levin et al 2004;Ren et al 2006;Eichlerová et al 2006;Daneshvar et al 2007a, b;Ayed et al 2008;Ali et al 2009;Wu et al 2009;Cheriaa and Bakhrouf 2009;Ayed et al 2010;Du et al 2011;Khataee et al 2011a, b;Shedbalkar and Jadhav 2011;Hu et al 2011;Abd-El-Kareem and Taha 2012); photocatalytic degradation (Hasnat et al 2003;Kominami et al 2003;Lv et al 2005;Yang et al 2005;Chen et al 2007;Sayılkan et al 2007aSayılkan et al , b, 2008Tayade et al 2007;Wang et al 2008a;Ju et al 2008;Asiltürk et al 2009;Prado and Costa 2009;Bansal et al 2009;Kaneva et al 2010;Liu et al 2010;Bojinova and Dushkin 2011; Maximum wavelength 618 nm Table 2 Applications and toxicity of Malachite green dye…”
Adsorption can be efficiently employed for the removal of various toxic dyes from water and wastewater. In this article, the authors reviewed variety of adsorbents used by various researchers for the removal of malachite green (MG) dye from an aqueous environment. The main motto of this review article was to assemble the scattered available information of adsorbents used for the removal of MG to enlighten their wide potential. In addition to this, various optimal experimental conditions (solution pH, equilibrium contact time, amount of adsorbent and temperature) as well as adsorption isotherms, kinetics and thermodynamics data of different adsorbents towards MG were also analyzed and tabulated. Finally, it was concluded that the agricultural solid wastes and biosorbents such as biopolymers and biomass adsorbents have demonstrated outstanding adsorption capabilities for removal of MG dye.
“…Many treatment methods have been developed to remove dyes from wastewater, which can be divided into physical, chemical and biological method such as photo-degradation (Nogueira et al, 2005;Wu et al, 1999), photo catalytic degradation (Hachem et al, 2001;Kominami et al, 2003;Sayılkan et al, 2007), biodegradation (Parshetti et al, 2006;Daneshvar et al, 2007) and adsorption (Zhang et al, 2008;Mendez et al, 2007). Adsorption techniques have potential for removing organic and inorganic pollutants from wastewater due to their high efficiency and ability to separate a wide range of compounds (Jain et al, 2007;.…”
“…MG photo-degradation pathway in dye-aquacultured mudfish Several recent investigations focused on MG photo-degradation only in MG aqueous solution (9,10). To the best of our information, however, there is still no report on the MG photo-degradation mechanism in sample tissue.…”
Section: Mg Degradation Profiles In Dye-administered Mudfishmentioning
confidence: 98%
“…The samples were removed from the UV apparatus for each of the specified time intervals (10,20,30,45, and 60 min) and allowed to cool until they reached room temperature. No juices were observed during the UV irradiation.…”
Section: Mg Administration and Uv Irradiation In Mudfishmentioning
confidence: 99%
“…Some promising technologies have been reported to MG degradation (9)(10)(11)(12). Most reports have focused on new photocatalysts, the experimental conditions, and the possibility of environmental applications.…”
Ultraviolet (UV) light induced photo-degradation of malachite green (MG) was investigated in the absence of photocatalysts. Photo-degraded intermediates were identified using LC with visible detection and LCelectrospray ionization-MS. Using this analysis, mechanisms for the MG decomposition in aqueous solution and in mudfish tissue were suggested. In aqueous condition, Nde-methylation and the decomposition of the conjugated structures were mainly observed. On the other hand, MG levels in mudfish continuously decreased until they reached a plateau owing to the decomposition of the conjugated structures. These results show that some chemicals in fish tissues could be photo-degraded by UV light without photocatalysts.
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