Abstract:Phosphorylation of 5.6-an hydro-3-O-benzyl-l,2-O-isopropylidene-~-glucofuranose with dipotassium hydrogen phosphate yields the corresponding 6-phosphate, which, after acidic hydrolysis and periodate cleavage between C-1 and C-2, gives the stable 2-O-benzyl-~-arabinofuranose 5-phosphate. Removal of the benzyl group by hydrogenolysis affords the title compound. In view of the known instability of pentose 5-phosphates D-arabinose 5-phosphate should be stored as its 2-O-benzyl derivative.
Durch Phosphorylierung der Anhydroglucofuranose (I) wird das als Ba‐Salz isolierte Phosphat (II) erhalten, das durch milde saure Hydrolyse in das Phosphat (III) übergeführt wird.
Durch Phosphorylierung der Anhydroglucofuranose (I) wird das als Ba‐Salz isolierte Phosphat (II) erhalten, das durch milde saure Hydrolyse in das Phosphat (III) übergeführt wird.
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