Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions

Горбунов, Д. Н.; Nenasheva, M. V.; Terenina, M. V.; Yu.S, Kardasheva; Naranov, E. R.; Bugaev, Aram L.; Солдатов, А. В.; Maximov, A. L.; Tilloy, S.; Monflier, Éric; Караханов, Э. А.

doi:10.1016/j.apcata.2022.118891

Cited by 13 publications

(3 citation statements)

References 139 publications

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“…The olefins conversion on these catalysts can reach up to ~100 %. At present, homogeneous catalytic systems with Rh(I) complexes have become the most widespread due to their high selectivity towards linear products [153] …”

Section: Hydroprocesses On Noble Metal Oxide Catalystsmentioning

confidence: 99%

Sustainable Production of Chemicals via Hydrotreating of CO₂ and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

Naranov

2024

ChemCatChem

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The noble metals are widely used in heterogeneous catalysis and automobile industry. The limited natural sources and high cost of noble metals dictates improving the efficiency of modern industry. This review considers the applications of noble metal oxide as potential solutions to the sustainability issues, including biomass conversion, CO2 capture and conversion, green fuel production, etc. Noble metal oxides with their different compositions (monometallic and bimetallic) and structures exhibit a wide range of properties in heterogeneous catalysis. Although platinum metals in an oxidized form may not be the most common choice in hydroprocesses; recently, there have been studies indicating that they were highly active and selective catalysts in hydrogenation and hydrogenolysis. This review outlines the most established noble metal oxide catalysts used in hydrogenation catalysis and shed the light on the relation of noble metal oxide species to catalyst selectivity based on state‐of‐the‐art techniques. Finally, the perspectives on the application of noble metal oxide catalysts to produce value‐added chemicals are discussed.

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Section: Hydroprocesses On Noble Metal Oxide Catalystsmentioning

confidence: 99%

Sustainable Production of Chemicals via Hydrotreating of CO₂ and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

Naranov

2024

ChemCatChem

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“…These CTFs‐based materials not only limited metal nanoparticles via the nitrogen functionalities of these networks, but also facilitated the separation of the products from the reaction mixture [8] . Recently, Karakhanov's group also contributed a systematic summary towards a series of phosphorus‐free and nitrogen‐containing catalytic system for hydroformylation [9] . However, these catalysts are difficult to achieve high olefin conversion and aldehyde selectivity.…”

Section: Introductionmentioning

confidence: 99%

“…[8] Recently, Karakhanov's group also contributed a systematic summary towards a series of phosphorus-free and nitrogen-containing catalytic system for hydroformylation. [9] However, these catalysts are difficult to achieve high olefin conversion and aldehyde selectivity.…”

Section: Introductionmentioning

confidence: 99%

Nitrogen‐containing Porous Organic Polymer Supported Rhodium Catalyst for Hydroformylation of Olefins

Lan,

Lu,

Yun

et al. 2023

ChemistrySelect

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The hydroformylation reaction of olefins with syngas (CO/H2) to manufacture aldehydes is one of the largest homogeneous catalytic processes. However, it is important to extend the use of Rh catalysts promoted by nitrogen ligands to heterogeneous system. In this study, a nitrogen‐containing porous organic polymer supported Rh catalyst (Rh/TImT‐TBPT) was successfully synthesized, as well as showed excellent catalytic activity (TOF=216 h−1) and selectivity of aldehydes (98 %) in the hydroformylation of 1‐octene. Furthermore, the catalytic performance of Rh/TImT‐TBPT in the hydroformylation of various olefins was also investigated, displaying outstanding results. The catalytic material was characterized by FT‐IR, XRD, XPS, TEM, SEM and TGA in detail. The characterization data showed that Rh species were highly dispersed on the support, leading to the good stability. More importantly, the Rh/TImT‐TBPT catalyst could be separated from the reaction system at the end of the hydroformylation, and then reused in the next cycle under optimized conditions.

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One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

Delolo,

dos Santos,

Gusevskaya

2024

ChemCatChem

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One‐pot synthetic procedures allow multiple chemical transformations circumventing the isolation of intermediates and thus saving time, energy and feedstocks. Within the scope of one‐pot processes, cascade, domino, or tandem procedures are even more efficient, as multiple reactions can occur in parallel. Hydroformylation is an industrially relevant reaction particularly suitable for this kind of methodology, as the primary products (aldehydes) are usually converted into compounds containing other functionalities. In addition to examples of transformations of the substrate before the hydroformylation step or the transformation of the aldehyde into other functionalities, we highlight a novel approach, in which an additional functionalization takes place in a remote site of the substrate molecule, along with the hydroformylation of the carbon‐carbon double bond.

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Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions

Cited by 13 publications

References 139 publications

Sustainable Production of Chemicals via Hydrotreating of CO₂ and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

Sustainable Production of Chemicals via Hydrotreating of CO₂ and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

Nitrogen‐containing Porous Organic Polymer Supported Rhodium Catalyst for Hydroformylation of Olefins

One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

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Phosphorus-free nitrogen-containing catalytic systems for hydroformylation and tandem hydroformylation-based reactions

Cited by 13 publications

References 139 publications

Sustainable Production of Chemicals via Hydrotreating of CO2 and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

Sustainable Production of Chemicals via Hydrotreating of CO2 and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

Nitrogen‐containing Porous Organic Polymer Supported Rhodium Catalyst for Hydroformylation of Olefins

One‐Pot Reactions in Different Sites: A New Approach in Hydroformylation‐Based Processes

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Sustainable Production of Chemicals via Hydrotreating of CO₂ and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts

Sustainable Production of Chemicals via Hydrotreating of CO₂ and Biomass Derived Molecules Using Heterogeneous Noble Metal Oxide Catalysts