Phosphaniminatokomplexe von Mangan und Cobalt mit Heterocubanstruktur

Mai, Hans-Joachim; Köcker, Rolf Meyer zu; Wočadlo, Sigrid; Massa, Werner; Dehnicke, Kurt

doi:10.1002/ange.19951071122

Cited by 19 publications

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“…[15] The m 3h 1 :h 1 :h 1 -bridging alkynyl metal motif is very well documented for the coinage metals Cu, Ag, and Au. [16,17] heterocubane clusters and only slightly longer than in Mn 6 H 6 (hmds) 6 (2.85622(3)-2.97627 (3) ). [16,17] heterocubane clusters and only slightly longer than in Mn 6 H 6 (hmds) 6 (2.85622(3)-2.97627 (3) ).…”

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Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn₄C₄ Cluster

et al. 2019

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While the coordination chemistry of monometallic complexes and the surface properties of extended metal particles are well understood, the control of metal nanocluster formation has remained challenging. The isolation of discrete metal clusters provides an especially rare snapshot at the nanoscale of cluster growth. The synthesis and full characterization of the first early-transition-metal alkynyl cubane and the first m 3 -alkynyl Mn 3 motif are reported. Scheme 1. Transition-metal clusters:S carcity of CO-free alkynyl metal clusters other than with coinage metals.Scheme 2. The m 3 -X-M motif in planar hydridomanganese and 3D alkynyl-manganese clusters (R = SiMe 3 ).Supportinginformation and the ORCID identification number for one of the authors of this article can be found under: https://doi.

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Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn₄C₄ Cluster

et al. 2019

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“…Von zweiwertigen Übergangsmetallen abgelei tete Phosphaniminato-Komplexe mit Heterocuban-Struktur vom Typ [MX(NPR3)]4 mit X = Cl, Br, I und R = Me, Et sind von Mangan [1,2], Cobalt [1,3] und Nickel [2] …”

Section: Introductionunclassified

Phosphanimin- und Phosphaniminato-Komplexe des Zinks. Kristallstrukturen von [ZnCl₂(Me₃SiNP(CH₂)₄CMe₃)]₂, [ZnI₂(Me₃SiNPEt₃)]₂, [ZnI₂{Me₂Si(NPEt₃)₂}] und [ZnBr(NPMe₃)]₄· CH₂Cl₂/ Phosphaneimine and Phosphoraneiminato Complexes of Zinc. Crystal Structures of [ZnCl₂(Me₃SiNP(CH₂)

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et al. 1997

Zeitschrift Für Naturforschung B

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The donor-acceptor complexes [ZnCl2(Me3SiNP(CH2)4CMe3)]2 (l)and [ZnI2(Me3SiNPEt3)]2 (2) have been prepared from the zinc dihalides and the corresponding silylated phosphaneimines in CH2C12. Thermolysis of 2 leads to the formation of [ZnI2(Me2Si(NPEt3)2)] (3). Znl2 and ZnBr2 react with the silylated phosphaneimines Me3SiNPR3 (R = Me, Et) in the presence of NaF at elavated temperatures to give the phosphoraneiminato complexes [ZnI(NPEt3)]4 (4),

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“…Wir berichten hier über Phosphanimin-Komplexe von M angan(II)halogeniden, die sich bei hohen Temperaturen unter Bil dung von tetram eren Phosphaniminatokomplexen [M nX(NPEt3)]4 mit H eterocubanstruktur zerset zen [5].…”

Section: Introductionunclassified

Phosphanimin-Komplexe von Mangan(II)halogeniden. Die Kristallstrukturen von [MnCl₂(Me₃SiNPEt₃)]₂, [Mnl₂(Me₃SiNPEt₃)₂] und [MnI₂(Me₂Si(NPEt₃)₂)] / Phosphaneimine Complexes of Manganese(II)halides. The Crystal Structures of [MnCl₂(Me₃SiNPEt₃)]₂, [Mnl₂(Me₃SiNPEt₃)₂] and [MnI₂(Me
Mai
¹
,
Wočadlo
²
,
Massa
³

et al. 1995
Zeitschrift Für Naturforschung B
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Phosphaniminatokomplexe von Mangan und Cobalt mit Heterocubanstruktur

Cited by 19 publications

References 25 publications

Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn₄C₄ Cluster

Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn₄C₄ Cluster

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Phosphaniminatokomplexe von Mangan und Cobalt mit Heterocubanstruktur

Cited by 19 publications

References 25 publications

Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn4C4 Cluster

Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn4C4 Cluster

Phosphanimin- und Phosphaniminato-Komplexe des Zinks. Kristallstrukturen von [ZnCl2(Me3SiNP(CH2)4CMe3)]2, [ZnI2(Me3SiNPEt3)]2, [ZnI2{Me2Si(NPEt3)2}] und [ZnBr(NPMe3)]4· CH2Cl2/ Phosphaneimine and Phosphoraneiminato Complexes of Zinc. Crystal Structures of [ZnCl2(Me3SiNP(CH2)

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Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn₄C₄ Cluster

Synthesis and Reactivity of an Early‐Transition‐Metal Alkynyl Cubane Mn₄C₄ Cluster