Metavalent bonding
is crucial for the determination of phase transition
and improvement of device performance in phase-change materials, which
are attracting interest for use in memory devices. Although monitoring
dielectric and phononic parameters provides a direct measure of the
metavalent bonding, the control of phase-change phenomena and metavalent
bonding in the dynamical regime has yet to be demonstrated. This study
reports the photoenhanced metavalent bonding and resulting hidden
metallic crystalline state of Ti-doped Sb2Te3, a representative phase-change material with ultralong sustainability.
Using ultrafast terahertz spectroscopy, Ti0.4Sb2Te3 was discovered to possess ultralong pump–probe
dynamics, which is retained over hundreds of picoseconds, unlike the
short-lived state of undoped Sb2Te3. Moreover,
for Ti0.4Sb2Te3 during the long-lived
transmission change, the infrared-active phonon is highly softened,
even more than the amount of a thermal phonon shift, indicating the
photoenhancement of lattice anharmonicity. Such a long-lived relaxation
implies photoinduced transition into a crystalline state of ultrastrong
metavalent bonding in Ti0.4Sb2Te3, on the basis of comparisons of the dynamical dielectric constant
and temporal phonon shift. Our results show the realization of photoengineering
of phase-change materials by tuning electron sharing or transferring.