2006
DOI: 10.1016/j.physc.2006.08.010
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Phase evolution during the melting and recrystallization of ceramic core in the (Bi,Pb)-2223 tape

Abstract: The phase evolution during melting and recrystallization of ceramic core in Ag-sheathed (Bi,Pb)-2223 monofilamentary tape has been studied. The tape was fabricated by PIT process with powders containing nearly pure (Bi,Pb)-2223 phase. Short samples were melted at 805ºC, 808ºC, 812ºC, 816ºC and 831ºC, slowly cooled down at 1.5ºC/hr. and quenched in air at room temperature. X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) were applied for the phase id… Show more

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Cited by 2 publications
(2 citation statements)
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References 9 publications
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“…In spite of this success, this technique has not been used to prepare tapes or multifilament materials at an industrial scale because it was thought that any melting would decompose the Bi 2223 phase and a long period of annealing at a lower temperature would be necessary to recover this phase; long annealing and even a partial melting of chemical precursors have been used to obtain the Bi 2223 phase. Recently, experiments have again shown that this phase can be rapidly recomposed after melting, in agreement with the previous work on magnetic texturing [30,31]. All these results indicate the existence, above the liquidus temperature, of unmelted crystals acting as crystal growth nuclei.…”
Section: Bi 2223supporting
confidence: 89%
“…In spite of this success, this technique has not been used to prepare tapes or multifilament materials at an industrial scale because it was thought that any melting would decompose the Bi 2223 phase and a long period of annealing at a lower temperature would be necessary to recover this phase; long annealing and even a partial melting of chemical precursors have been used to obtain the Bi 2223 phase. Recently, experiments have again shown that this phase can be rapidly recomposed after melting, in agreement with the previous work on magnetic texturing [30,31]. All these results indicate the existence, above the liquidus temperature, of unmelted crystals acting as crystal growth nuclei.…”
Section: Bi 2223supporting
confidence: 89%
“…Then, Bi2223 intrinsic nuclei exist in the melt. This new route is extremely sensitive to the temperature profile and is dependent of the local Pb content [40]. This result confirms the possibility to texture Ag-sheathed Bi,Pb(2223) tapes by means of a scrolling continuous heat treatment under a magnetic field.…”
Section: Ag-sheated Tapes Of Bi2sr2ca2cu3o8+xsupporting
confidence: 73%