1988
DOI: 10.1016/0022-5088(88)90170-1
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Phase diagram of the GaAsSb system

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Cited by 27 publications
(13 citation statements)
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“…Thus, a relative change in these parameters will determine the Sb composition in the NWs for a given influx composition. Due to the lower volatility of Sb as compared to As, the decrease in Ψ Sb will be relatively higher than in Ψ As with a decrease in temperature, and the liquid-solid phase diagram of the GaAs-GaSb system also suggests that the K Sb /K As ratio will be higher 40 at lower growth temperatures. Consequently, the Sb composition in the NWs will be enhanced when grown at lower substrate temperatures, which is consistent with our experimental observations.…”
Section: Resultsmentioning
confidence: 99%
“…Thus, a relative change in these parameters will determine the Sb composition in the NWs for a given influx composition. Due to the lower volatility of Sb as compared to As, the decrease in Ψ Sb will be relatively higher than in Ψ As with a decrease in temperature, and the liquid-solid phase diagram of the GaAs-GaSb system also suggests that the K Sb /K As ratio will be higher 40 at lower growth temperatures. Consequently, the Sb composition in the NWs will be enhanced when grown at lower substrate temperatures, which is consistent with our experimental observations.…”
Section: Resultsmentioning
confidence: 99%
“…The proposed phase diagram of the Ga‐containing skutterudites at 923 K is shown in Figure a, and is based on general knowledge of binary phase diagrams 51–55. The related binary phases of Ga, Co, and Sb are shown on the axes including the known regions of solid or liquid solubility for the binary compounds and a rough estimate of the solubility of the ternary compounds (red regions).…”
Section: Resultsmentioning
confidence: 99%
“…Since in this system c,"&0, the energy c"ofa single cluster is lower than the energy of a phase exhibiting a few clusters. As the temperature is lowered, hence the entropy term -TbS becomes less important, the system acts to enrich 8 X"), hence reducing hH(x, T), as seen in Fig. 11.…”
Section: G Excess Cluster Probabilitiesmentioning
confidence: 88%