“… , All samples are then subjected to reaction kinetic curve studies within 20 min to assess catalytic activity. Fe 1 -NC exhibited the most excellent POD-like catalytic performance among all SAzymes (Figure A), proving that the Fe-N 4 active site center could dominate the catalytic activity. − Of note, as revealed by the kinetic results of 13 DAzymes (Figure B), the Fe-series DAzymes have better catalytic performance. The absorbances at 20 min of Fe 1 Co 1 -NC, Fe 1 Cu 1 -NC, Fe 1 Mn 1 -NC, Fe 1 Ni 1 -NC, and Fe 1 Ru 1 -NC are 1.1791, 0.6547, 0.5247, 0.3454, and 0.3087, respectively, which are 4.5 times, 2.5 times, 2.0 times, 1.3 times, and 1.2 times higher than that of Fe 1 -NC (0.2611).…”