Perspektiven gekoppelter organisch‐anorganischer Nanostrukturen für Ladungs‐ und Energietransferanwendungen

The new heteroleptic tungsten iodide cluster compound [W 6 I 12 (NCC 6 H 5 ) 2 ] is presented. The synthesis is carried-out from Cs 2 W 6 I 14 and ZnI 2 under solvothermal conditions in benzonitrile solution, yielding red cube-shaped crystals. [W 6 I 12 (NCC 6 H 5 ) 2 ] represents a heteroleptic [W 6 I 8 ]-type cluster bearing four apical iodides and two benzonitrile ligands. Molecular [W 6 I 12 (NCC 6 H 5 ) 2 ] clusters form a robust hydrogen bridged crystal structure with high thermal stability and high resistibility against hydrolysis. The electronic structure is analyzed by quantum chemical methods of the calculated electron localization function (ELF) and the band structure. Photoluminescence measurements are performed to verify and describe the photophysical properties of [W 6 I 12 (NCC 6 H 5 ) 2 ]. Finally, the photocatalytic properties of [W 6 I 12 (NCC 6 H 5 ) 2 ] are evaluated as a proof-of-concept.

show abstract

The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W₆I₁₂(NCC₆H₅)₂]

Pachel

Ströbele

Romao

et al. 2023

Eur J Inorg Chem

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Perspektiven gekoppelter organisch‐anorganischer Nanostrukturen für Ladungs‐ und Energietransferanwendungen

Abstract: 2020 Die Autoren. Verçffentlicht von Wiley-VCH GmbH. Dieser Open Access Beitrag steht unter den Bedingungen der Creative Commons Attribution License, die jede Nutzung des Beitrages in allen Medien gestattet, sofern der ursprüngliche Beitrag ordnungsgemäß zitiert wird.

Cited by 1 publication

References 244 publications

The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W₆I₁₂(NCC₆H₅)₂]

The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W₆I₁₂(NCC₆H₅)₂]

Contact Info

Product

Resources

About

Perspektiven gekoppelter organisch‐anorganischer Nanostrukturen für Ladungs‐ und Energietransferanwendungen

Abstract: 2020 Die Autoren. Verçffentlicht von Wiley-VCH GmbH. Dieser Open Access Beitrag steht unter den Bedingungen der Creative Commons Attribution License, die jede Nutzung des Beitrages in allen Medien gestattet, sofern der ursprüngliche Beitrag ordnungsgemäß zitiert wird.

Cited by 1 publication

References 244 publications

The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W6I12(NCC6H5)2]

The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W6I12(NCC6H5)2]

Contact Info

Product

Resources

About

The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W₆I₁₂(NCC₆H₅)₂]

The Remarkably Robust, Photoactive Tungsten Iodide Cluster [W₆I₁₂(NCC₆H₅)₂]