Performance and stability of Ruddlesden-Popper La2NiO4+δ oxygen electrodes under solid oxide electrolysis cell operation conditions

Tong, Xin; Zhou, Fengjiao; Yang, Shengbing; Zhong, Shengwen; Wei, Mingrui; Liu, Yihui

doi:10.1016/j.ceramint.2017.05.130

Cited by 55 publications

(34 citation statements)

References 49 publications

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“…Therefore, they are promising materials for technological devices such as solid oxide fuel cells, oxygen membranes, sensors, etc. [6][7][8][9]. They are also a special class of materials into which oxygen ions can be intercalated reversibly even at ambient temperature using electrochemical methods [10,11], and the oxygen overstoichiometry (δ) can be tuned between 0 δ 0.25.…”

Section: Introductionmentioning

confidence: 99%

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ (
Maity
¹
,
Ceretti
²
,
Keller
³

et al. 2019
Phys. Rev. Materials
7
5
12
0
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Section: Introductionmentioning

confidence: 99%

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ (
Maity
¹
,
Ceretti
²
,
Keller
³

et al. 2019
Phys. Rev. Materials
7
5
12
0
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“…Thus, the influence on the amount of Sr may influence the formation of the spinel structure, Nickel-based perovskite catalysts: synthesis and catalytic tests in the production of syngas (Catalisadores à base de níquel com estrutura perovskita: síntese e testes catalíticos na produção de gás de síntese) La 2 NiO 4 , which, like the perovskite structure, presents high thermal and mechanical stability [10,11]. In addition, it offers resistance to wear related to the reaction conditions and is widely used in the study of solid-oxide fuel cell (SOFC) [10,12]. In general, the perovskite properties are influenced by the synthesis method, calcination conditions (temperature, time and atmosphere) and substitutions at sites A and/or B.…”

Section: Introductionmentioning

confidence: 99%

Nickel-based perovskite catalysts: synthesis and catalytic tests in the production of syngas

et al. 2018

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La 1-x Sr x NiO 3 (x= 0.0, 0.3 or 0.7) perovskite-type oxides were synthesized using the modified proteic gel method and using collagen as an organic precursor. Catalysts of La 1-x Sr x NiO 3 /Al 2 O 3 were obtained using the wet impregnation method. The synthesized catalysts were characterized by X-ray diffraction, surface area and temperature-programmed reduction. The catalysts were evaluated in the partial oxidation reaction of methane, and the levels of selectivity to CO, CO 2 , H 2 and H 2 O were determined. Among the catalysts studied, the catalyst LaNiO 3 /Al 2 O 3 had the highest methane conversion level (78%) and higher H 2 selectivity (55%). Keywords: La 1-x Sr x NiO 3 , perovskite-type oxides, modified proteic gel method, partial oxidation of methane. Resumo Perovskitas do tipo

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“…However, the stability of Ruddlesden–Popper phase is controversial according to the reported results. For La 2 NiO 4+ δ anode, evident degradation is observed after operating at 500 mA cm −2 and 750 °C for 48 h with the formation of La 3 Ni 2 O 7 and La 4 Ni 3 O 10 phases. While for Pr 2 NiO 4+ d anode, partial decomposition of the Pr 2 NiO 4+ d phase into PrNiO 3 and PrO 2‐ y causes oscillation in current density but does not depress the electrochemical performance of SOEC.…”

Section: Anodementioning

confidence: 99%

High‐Temperature CO₂ Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects

et al. 2019

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which has caused serious global warming. According to Intergovernmental Panel on Climate Change, global warming of 1.5 °C above preindustrial levels will come true by 2055 and bring about severe environmental and ecological issues, [2] such as ocean acidification, sea level rise, and species extinction. Therefore, it is urgently needed to reduce the atmospheric CO 2 concentration. [3] Apart from utilizing renewable energy resources to substitute for fossil fuels, CO 2 capture and storage (CCS) processes, and CO 2 capture and utilization (CCU) processes have been developed to effectively diminish the existing atmospheric CO 2 concentration. [4] The CCS processes are often expensive and laborious, and face the risk of CO 2 leakage, while the CCU processes are able to convert the captured CO 2 to value-added carbon-containing chemicals powered by external energy and has attracted more and more research interests recently. However, the conversion of CO 2 to target products is relatively difficult due to its extremely stable CO bonds. Several approaches for CO 2 conversion have been developed, such as photosynthesis, thermocatalytic reduction, electrochemical reduction, and photochemical conversion. Compared with other approaches, electrochemical reduction is more attractive because of two reasons: 1) electrochemical reduction process is controllable through adjusting the applied voltage and reaction temperature, and 2) the process can utilize renewable energy resources such as wind, solar, hydroelectric, and geothermal energies to electrochemically convert CO 2 to useful chemicals, which forms a carbon-neutral energy cycle and simultaneously provides an efficient storage method for renewable energy resources.Several types of electrolysis cell have been systematically investigated for CO 2 electroreduction as listed in Table 1. The first type operates in H-shaped electrochemical cells with liquid electrolyte at low temperatures (<100 °C).[5] Gaseous CO 2 reactant is dissolved into the liquid electrolyte and transported to the electrode surface, which is subsequently electroreduced to CO, HCOOH, CH 4 , C 2 H 4 , C 2 H 5 OH, and so on. [1,6] Although high Faradaic efficiency of products from CO 2 electroreduction has been achieved by exploring efficient catalysts recently, the current density of CO 2 electrolysis is relatively low due to the low CO 2 solubility and the competitive High-temperature CO 2 electrolysis in solid-oxide electrolysis cells (SOECs) could greatly assist in the reduction of CO 2 emissions by electrochemically converting CO 2 to valuable fuels through effective electrothermal activation of the stable CO bond. If powered by renewable energy resources, it could also provide an advanced energy-storage method for their intermittent output. Compared to low-temperature electrochemical CO 2 reduction, CO 2 electrolysis in SOECs at high temperature exhibits higher current density and energy efficiency and has thus attracted much recent attention. The history of its development and its fundamental mech...

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Performance and stability of Ruddlesden-Popper La2NiO4+δ oxygen electrodes under solid oxide electrolysis cell operation conditions

Cited by 55 publications

References 49 publications

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ (
Maity
¹
,
Ceretti
²
,
Keller
³

et al. 2019
Phys. Rev. Materials
7
5
12
0
View full text Add to dashboard Cite

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ (
Maity
¹
,
Ceretti
²
,
Keller
³

et al. 2019
Phys. Rev. Materials
7
5
12
0
View full text Add to dashboard Cite

Nickel-based perovskite catalysts: synthesis and catalytic tests in the production of syngas

High‐Temperature CO₂ Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects

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Performance and stability of Ruddlesden-Popper La2NiO4+δ oxygen electrodes under solid oxide electrolysis cell operation conditions

Cited by 55 publications

References 49 publications

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ ( Maity1, Ceretti2, Keller3 et al. 2019Phys. Rev. Materials75120View full textAdd to dashboardCite

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ ( Maity1, Ceretti2, Keller3 et al. 2019Phys. Rev. Materials75120View full textAdd to dashboardCite

Nickel-based perovskite catalysts: synthesis and catalytic tests in the production of syngas

High‐Temperature CO2 Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects

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Resources

About

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ (
Maity
¹
,
Ceretti
²
,
Keller
³

et al. 2019
Phys. Rev. Materials
7
5
12
0
View full text Add to dashboard Cite

Structural disorder and magnetic correlations driven by oxygen doping in Nd2NiO4+δ (
Maity
¹
,
Ceretti
²
,
Keller
³

et al. 2019
Phys. Rev. Materials
7
5
12
0
View full text Add to dashboard Cite

High‐Temperature CO₂ Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects