Efficient acquiring and removal of
a hazardous particulate matter
(PM) have significant effects on human health. Here, we illustrate
the fabrication of a superwetting electrospun polydimethylsiloxane/polymethyl
methacrylate (PDMS/PMMA) membrane (EPPM) with multifunctional performance
for PM2.5 capture and microdroplet transfer, where PMMA
was added as a carrier polymer to the superhydrophobic PDMS, which
has very low cohesive energy density. The obtained EPPM, which is
composed of special bead-on-string fibers with a mean fiber diameter
of 350 nm, shows a porous structure with an aperture of 7.87 μm
(calculated by the bubble pressure method) and superb thermostability
(up to 325 °C). The EPPM possesses an excellent PM2.5 purification efficiency of nearly up to 100% at a very low pressure
drop (70 Pa, <0.07% of the atmospheric pressure) under the condition
of high humidity (96 ± 3%), which is greatly advantageous over
those hydrophilic filters frequently suffering the drawbacks of low
efficiency or total invalidation in humid environments. In addition,
benefitting from the superhydrophobic and strong adhesive properties
of the membrane surface, the EPPM could complete the trace aqueous
sample analysis such as “robotic hand” from superhydrophobic
to hydrophilic surfaces without any contamination or loss and hold
a high contact angle of 161.6° for water. Altogether, the EPPM
may have technological advantages as a kind of novel fibrous filter
in diverse environmental applications, including PM2.5 capture,
separation, microdroplet transfer, and so on.