Propensity score matching is widely used in various fields of research, including psychology, medicine, education, and sociology. It is usually applied to find a matched control group for a treatment group. In the present article, we suggest that propensity score matching might also be used to construct item sets matched for different parameters. We constructed stimuli to illustrate the use of propensity score matching in item construction for the exemplary cases of numerical cognition research and reading research. In particular, we provide a step-by-step approach, using the statistics software R, for how to apply propensity score matching for constructing matched stimuli. This approach involves deciding on a population of stimuli, determining and calculating the covariates, and finally applying the propensity-matching method to find a set of items matched to another predefined set. Thereby, we were able to construct well-matched item sets for both examples. Hence, we conclude that the propensityscore-matching method is useful for constructing matched stimuli. Further cases of application are discussed.