2003
DOI: 10.1021/nl034412s
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Patterned Transfer of Metallic Thin Film Nanostructures by Water-Soluble Polymer Templates

Abstract: Water-soluble polymer templates are replicated from surface patterns by spin-casting a poly(vinyl alcohol) film-forming solution that undergoes a room-temperature evaporation process to solidify in less than 1 min with lateral resolution of sub-100 nm. The patterned polymer templates are deposited with metal and coupled to substrate surfaces by methods that may include photocurable materials, two-component reaction systems, or direct bonding without an intervening adhesion layer. Water is used to dissolve the … Show more

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Cited by 62 publications
(42 citation statements)
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“…For patterning on a curved surface, we used patterned polyvinyl alcohol (PVA) foils as stamps (Schaper 2003) as the material is transparent to UV light, thereby exposing the filmstamp interface to UV light for making the patterns per- manent. In case of patterning of curved surfaces too, the pattern transfer takes place directly in the solid phase, in contrast to existing reported methods where the liquid is heated beyond its glass transition temperature and the patterning takes place in liquid state.…”
Section: Resultsmentioning
confidence: 99%
“…For patterning on a curved surface, we used patterned polyvinyl alcohol (PVA) foils as stamps (Schaper 2003) as the material is transparent to UV light, thereby exposing the filmstamp interface to UV light for making the patterns per- manent. In case of patterning of curved surfaces too, the pattern transfer takes place directly in the solid phase, in contrast to existing reported methods where the liquid is heated beyond its glass transition temperature and the patterning takes place in liquid state.…”
Section: Resultsmentioning
confidence: 99%
“…17 PVA polymer materials offer several advantages, including low toxicity, low cost, high Young's modulus, and solubility in water. 18 Furthermore PVA has already been widely used as a low cost binder in the commercial production of ceramics. 19 …”
Section: Introductionmentioning
confidence: 99%
“…18) PVA polymer materials offer several advantages, including low toxicity, low cost, high Young's modulus, and solubility in water. 19) Furthermore PVA has already been widely used as a low cost binder in the commercial production of ceramics.…”
Section: Introductionmentioning
confidence: 99%