State-and target-isotope-dependent cross sections for electron capture in collisions of N 4+ (2s) with H(1s), D(1s), and T(1s) are presented for the energy range 0.01-6000 eV amu −1 . Results are given for capture via radial coupling into the N 3+ 2s3s 1 S, 2s3p 1 P o , 2s3d 1 D, 2s3s 3 S, 2s3p 3 P o , 2s3d 3 D, and 2p3s 3 P o states and are obtained through a close-coupled, quantummechanical, molecular-orbital method. Fully ab initio molecular data determined with the spincoupled valence-bond method are incorporated. Rate coefficients for temperatures between 1000 and 10 6 K are also presented. Applications to astrophysical environments and laboratory plasmas are addressed. The importance of state-dependent parameters for the modelling of nebulae emission lines and for fusion plasma impurity diagnostics and the potential significance of isotope effects to models of the edge region of a tokamak device are briefly discussed.