Palladium catalyzed thiono-thiolo allylic rearrangement of o-allyl phosphoro- and phosphonothionates

Yamada, Yoshimi; Mukai, Kunio; Yoshioka, Hirosuke; Tamaru, Yoshinao; Yoshida, Zen‐ichi

doi:10.1016/s0040-4039(01)86776-9

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Application Of Catalytic Reaction1

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Cited by 23 publications

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“…61 An equilibration of allylic isomers in which the leaving group returns at the allylically related carbon has also been noted.39,46,62 O-Allyl phosphorothionates equilibrate with S-allyl phosphorothiolates in the presence of 5-a type of reaction that may be useful for heteroatom interconversion. 63 Isomerization of vinyl epoxides to dienols and ß, -unsaturated ketones are envisioned to involve these intermediates.64…”

Section: Application Of Catalytic Reactionmentioning

confidence: 99%