Oxygen defect-mediated NiCo2O4 nanosheets as the electrode for pseudocapacitors with improved rate capability
Wen You,
Mengyuan Li,
Qiong Li
et al.
Abstract:Transition metal oxide-based supercapacitors have attracted much attention due to the high theoretical specific capacitances. However, due to insufficient utilization ratio and poor intrinsic conductivity of active materials, the rate...
“…and Power density = Energy density t d (5) where V 0 is the maximum voltage to charge the supercapacitor, Q is the net charge accumulated by the device, i is the constant current applied during the charge/discharge process, and t c is the charging period. Equation ( 4) is normalized with an appropriate parameter and a factor of 3600 yields, resulting in watt-hour units.…”
Section: Electrochemical Analysismentioning
confidence: 99%
“…In the area of energy storage, supercapacitors have emerged as formidable candidates, supported by their distinct power density, rapid charge-discharge profiles, and sustained cycle durability [ 1 , 2 , 3 ]. These electrochemical storage systems predominantly segregate into two categories: electric double-layer capacitors (EDLCs) and pseudocapacitors [ 4 , 5 ]. The operational mechanism of EDLCs is anchored in the reversible adsorption of ions at the electrode-electrolyte interface, primarily facilitated by electrostatic forces, marking a non-faradaic process [ 6 ].…”
The development of efficient energy storage systems is critical in the transition towards sustainable energy solutions. In this context, the present work investigates the viability of using orange juice, as a promising and sustainable precursor, for the synthesis of activated carbon electrodes for supercapacitor technologies. Through the carbonization-activation process and controlling the preparation parameters (KOH ratio and activation time), we have tailored the specific surface area (SSA) and pore size distribution (PSD) of the resulting carbon materials—crucial parameters that support supercapacitive performance. Several spectroscopic, morphological, and electrochemical techniques are used to characterize the obtained carbon materials. In particular, our optimization efforts revealed that a 5:1 KOH ratio with an activation time up to 120 min produced the highest SSA of about 2203 m2/g. Employing these optimal conditions, we fabricated symmetric coin cell supercapacitors using Na2SO4 as the electrolyte, which exhibited interesting specific capacitance (~56 F/g). Durability testing over 5000 cycles sustained the durability of the as-made activated carbon electrodes, suggesting an excellent retention of specific capacitance. This study not only advances the field of energy storage by introducing a renewable material for electrode fabrication but also contributes to the broader goal of waste reduction through the repurposing of food byproducts.
“…and Power density = Energy density t d (5) where V 0 is the maximum voltage to charge the supercapacitor, Q is the net charge accumulated by the device, i is the constant current applied during the charge/discharge process, and t c is the charging period. Equation ( 4) is normalized with an appropriate parameter and a factor of 3600 yields, resulting in watt-hour units.…”
Section: Electrochemical Analysismentioning
confidence: 99%
“…In the area of energy storage, supercapacitors have emerged as formidable candidates, supported by their distinct power density, rapid charge-discharge profiles, and sustained cycle durability [ 1 , 2 , 3 ]. These electrochemical storage systems predominantly segregate into two categories: electric double-layer capacitors (EDLCs) and pseudocapacitors [ 4 , 5 ]. The operational mechanism of EDLCs is anchored in the reversible adsorption of ions at the electrode-electrolyte interface, primarily facilitated by electrostatic forces, marking a non-faradaic process [ 6 ].…”
The development of efficient energy storage systems is critical in the transition towards sustainable energy solutions. In this context, the present work investigates the viability of using orange juice, as a promising and sustainable precursor, for the synthesis of activated carbon electrodes for supercapacitor technologies. Through the carbonization-activation process and controlling the preparation parameters (KOH ratio and activation time), we have tailored the specific surface area (SSA) and pore size distribution (PSD) of the resulting carbon materials—crucial parameters that support supercapacitive performance. Several spectroscopic, morphological, and electrochemical techniques are used to characterize the obtained carbon materials. In particular, our optimization efforts revealed that a 5:1 KOH ratio with an activation time up to 120 min produced the highest SSA of about 2203 m2/g. Employing these optimal conditions, we fabricated symmetric coin cell supercapacitors using Na2SO4 as the electrolyte, which exhibited interesting specific capacitance (~56 F/g). Durability testing over 5000 cycles sustained the durability of the as-made activated carbon electrodes, suggesting an excellent retention of specific capacitance. This study not only advances the field of energy storage by introducing a renewable material for electrode fabrication but also contributes to the broader goal of waste reduction through the repurposing of food byproducts.
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