2010
DOI: 10.1002/9783527630318
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Oxide Scale Behavior in High Temperature Metal Processing

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Cited by 75 publications
(80 citation statements)
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“…The approaches developed earlier for joint numerical solution of the heat and non-equilibrium mass transfer in gaseous and solid phases for investigation of alloying kinetics during laser treatment of metals offer possibilities to take into consideration elementary processes defining kinetics of gas-solid interactions such as molecule dissociation, chemisorptions of the dissociated atoms, energy transferred to the metal particles during the dissociation process and intensity of gas emission out of the metal [43,44]. A detailed finite element analysis using a physically based oxide-scale model can be a crucial aspect towards understanding and prediction of oxide-scale behaviour [45]. Metallurgical mechanisms, for example alloying when processing metal-metal powder mixtures or changes in the state of aggregation under semisolid conditions, are considered and modelled in the metallurgical submodel, taking into account the obtained history of the temperature field including heating and cooling rates.…”
Section: Model Of Powder Bed Generationmentioning
confidence: 99%
“…The approaches developed earlier for joint numerical solution of the heat and non-equilibrium mass transfer in gaseous and solid phases for investigation of alloying kinetics during laser treatment of metals offer possibilities to take into consideration elementary processes defining kinetics of gas-solid interactions such as molecule dissociation, chemisorptions of the dissociated atoms, energy transferred to the metal particles during the dissociation process and intensity of gas emission out of the metal [43,44]. A detailed finite element analysis using a physically based oxide-scale model can be a crucial aspect towards understanding and prediction of oxide-scale behaviour [45]. Metallurgical mechanisms, for example alloying when processing metal-metal powder mixtures or changes in the state of aggregation under semisolid conditions, are considered and modelled in the metallurgical submodel, taking into account the obtained history of the temperature field including heating and cooling rates.…”
Section: Model Of Powder Bed Generationmentioning
confidence: 99%
“…As the stock enters the roll gap, it is drawn in by frictional contact with the roll, which is moving faster than the stock surface at entry. This produces a longitudinal tensile stress in the stock surface ahead of contact with the roll [13,14]. The oxide scale can have transvers cracks or delamination by the tensile stress [14,15].…”
Section: Introductionmentioning
confidence: 99%
“…Hcp a o = 3.607; c o = 3.925 [66] 44.22 125 [61] 1.5 CoO cubic a o = 4.254 [67,68] 75.44 189 [66] 1.12 [62] NiO cubic a o = 4.173 [66,68] 72.67 230 to 260 [62,63] 1.5 [62] CrO cubic a o = 4.1 [69] 68.92 -1.5 NiCr 2 O 4 cubic a o = 8.32 [70] 573.9 106.6 [62] 0.57 [62] FeO cubic a o = 4.334 [72] 81.41 130 [74] 1.7 [75] a-Fe 2 O 3 rhombohedral a o = 4.99; c o = 13.61 [73] 338.6 219 [74] 1.7 [75] c-Fe 2 O 3 cubic a o = 8.40 [73] 591.92 208 [74] 1.7 [75] parameters that enhance K th also reduce the crack growth rates at K > K th by reducing the near-tip crack driving force. The beneficial effects of transformation toughening, however, diminish with increasing K levels above K th as the relaxed crack-tip stress field approaches the K-field, as shown in Figure 9.…”
Section: ½20mentioning
confidence: 99%