Au-containing nanolaminated carbides MoAuC and Mo(AuGa)C were synthesized by a thermally induced substitutional reaction in MoGaC and MoGaC, respectively. The Au substitution of the Ga layers in the structures was observed using cross-sectional high-resolution scanning transmission electron microscopy. Expansion of c lattice parameters was also observed in the Au-containing phases compared to the original phases. Energy dispersive spectroscopy detected residual Ga in Au-substituted layers of both phases with a peculiar Ga in-plane ordering for Au : Ga = 9 : 1 ratio along the Au-Ga layers in Mo(AuGa)C. These results indicate a generalization of the Au substitution reaction for the A elements in MAX phases.