“…Owing to the inherent molecular nature, the long-chain IL molecules can self-assemble in aqueous media to form micelles, vesicles, lyotropic liquid crystals, and gels, etc. 4 The self-assembly of ILs make it suitable for a range of application such as liquid-solid extraction, 5 corrosion protection, 6 synthesis of functionalized carbon nanotubes, 7 synthesis of CuO nano-structures, 8 phase-transfer catalysts, 9 oil recovery, 10 drug/gene delivery systems, 11 dispersants of petroleum asphaltenes, 12 green solvents of carbohydrate, 13 cosmetics 14 and textile industry. 15 Therefore, micellization behavior of ILs has become one of the intriguing objects in the eld of colloid and interface chemistry.…”