Osmium thioselenochloride Os2S6Se2Cl8: Synthesis, cluster isolation, and structure

Волков, С. В.; Gladyshevskii, R.; Mironov, Yuri V.; Demchenko, P.; Yanko, O. G.; Смоленцев, А. И.; Fokina, Z. A.; Khar’kova, L. B.; Baranets, Sviatoslav

doi:10.1134/s1070328412030104

Cited by 4 publications

(1 citation statement)

References 8 publications

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“…At transition‐metal compounds in higher oxidation states, the formation of a variety of metal halide sulfide clusters was observed . The composition of the furnished clusters strongly depends on the reaction conditions and the ratios of starting compounds, as for instance reported for the reaction of [OsO 4 ] ( 5 ) towards S 2 Cl 2 . Additional sulfur or selenium in the reaction mixture seems to be a suitable tool to induce the formation of bridging polysulfide ligands or mixed polychalcogene entities in the clusters …”

Section: Sulfur(i)/(ii) Compoundsmentioning

confidence: 89%

Reactivity of Binary and Ternary Sulfur Halides towards Transition‐Metal Compounds

Dirican

Pfister

Wozniak

et al. 2020

Chemistry A European J

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Binary sulfur fluorides exhibit an interesting reactivity towards transition metal complexes. They open up routes for the generation of sulfur‐containing building blocks. Often ligands with particular properties can be constructed. This includes their ability to transfer sulfur atoms or polysulfide units as well as fluorination reactions. This Minireview provides an insight into the reactivity of the binary and ternary sulfur halides S2Cl2, SCl2, SF4, SF6 and SF5Cl towards transition‐metal compounds.

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Section: Sulfur(i)/(ii) Compoundsmentioning

confidence: 89%

Reactivity of Binary and Ternary Sulfur Halides towards Transition‐Metal Compounds

Dirican

Pfister

Wozniak

et al. 2020

Chemistry A European J

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Mixed‐Valent Selenium Ligands in the Uncharged Iridium Complexes [Ir₄Se₁₀Br₁₆] and [Ir₆Se₈Cl₃₀]

2015

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The reaction of Ir with Se and SeBr 4 at 200°C yields shiny vermillion slate-like crystals of the new compound Ir 4 Se 10 Br 16 . Single-crystal X-ray diffraction revealed an orthorhombic unit cell, space group Pccn, with lattice parameters a = 1515.0(1) pm, b = 1534.4(1) pm, and c = 1514.5(1) pm at 296(1) K. The crystal structure consists of uncharged tetranuclear iridium complexes [Ir 4 Se 10 Br 16 ] with C 2 symmetry. In the [(Ir 3+ ) 4 (μ 4 -η 2 -Se 2 2-) 2 (μ-η Se -[SeBr] -) 2 (η Se -SeBr 2 ) 4 (μ-Br -) 2 (Br -) 4 ] complex, each of the iridium atoms is coordinated octahedrally by four selenium and two bromine atoms. Selenium adopts three different oxidation states: -I in the fourfold-bonded diselenide dumbbell, Ϯ0 in the bridging [a]

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Prediction of electronic and optical properties of monoclinic 1T’-phase OsSe2 monolayer using DFT principles

Moucherek

Santos

Novais

et al. 2022

Materials Today Communications

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Osmium thioselenochloride Os2S6Se2Cl8: Synthesis, cluster isolation, and structure

Cited by 4 publications

References 8 publications

Reactivity of Binary and Ternary Sulfur Halides towards Transition‐Metal Compounds

Reactivity of Binary and Ternary Sulfur Halides towards Transition‐Metal Compounds

Mixed‐Valent Selenium Ligands in the Uncharged Iridium Complexes [Ir₄Se₁₀Br₁₆] and [Ir₆Se₈Cl₃₀]

Prediction of electronic and optical properties of monoclinic 1T’-phase OsSe2 monolayer using DFT principles

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Osmium thioselenochloride Os2S6Se2Cl8: Synthesis, cluster isolation, and structure

Cited by 4 publications

References 8 publications

Reactivity of Binary and Ternary Sulfur Halides towards Transition‐Metal Compounds

Reactivity of Binary and Ternary Sulfur Halides towards Transition‐Metal Compounds

Mixed‐Valent Selenium Ligands in the Uncharged Iridium Complexes [Ir4Se10Br16] and [Ir6Se8Cl30]

Prediction of electronic and optical properties of monoclinic 1T’-phase OsSe2 monolayer using DFT principles

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Mixed‐Valent Selenium Ligands in the Uncharged Iridium Complexes [Ir₄Se₁₀Br₁₆] and [Ir₆Se₈Cl₃₀]