2015
DOI: 10.1103/physrevb.92.115203
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Origin of the positive spin-12photoluminescence-detected magnetic resonance in π-conjugated materials and devices

Abstract: The spin-1/2 single modulation (SM) and double modulation (DM) photoluminescence (PL) detected magnetic resonance (PLDMR) in poly(2-methoxy-5-(2'-ethyl)-hexoxy-1,4-phenylene vinylene) (MEH-PPV) films and poly(3-hexylthiophene) (P3HT) films is described, analyzed, and discussed. In particular, the models based on spin-dependent recombination of charge pairs (SDR) and triplet-polaron quenching (TPQ) are evaluated. By analyzing the dependence of the resonance amplitude on the microwave chopping (modulation) frequ… Show more

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Cited by 8 publications
(13 citation statements)
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“…In fact, the EDMR and ELDMR signals of OLEDs were previously explained by being due to the trions. 25,26 Contributions from the former trions can be examined from EDMR or ELDMR responses at the half…”
Section: A Esr Characteristicsmentioning
confidence: 99%
“…In fact, the EDMR and ELDMR signals of OLEDs were previously explained by being due to the trions. 25,26 Contributions from the former trions can be examined from EDMR or ELDMR responses at the half…”
Section: A Esr Characteristicsmentioning
confidence: 99%
“…In this case, device current changes will, of course, also induce recombination rate changes. An example of a spin-dependent transport mechanism which has previously been resolved directly in MEH-PPV devices is the quenching interaction between triplet excitons and charge carriers, the socalled triplet exciton-polaron mechanism [14,[43][44][45][46][47][48][49]. This process depends on triplet density and triplet lifetime, and therefore on temperature and exhibits clear signatures of s=1 triplet species in the half-field magnetic resonance.…”
Section: Introductionmentioning
confidence: 99%
“…The mechanism of PLDMR and PCDMR signals in polymer diodes has been discussed in several references [16,17,20,21]. Shinar and co-workers regarded spin-dependent reactions between TEs and polarons as relevant to the PLDMR mechanism [17,22]. However, the intersystem crossing from SE to TE in MEH-PPV was predicted to be inefficient [23,24].…”
mentioning
confidence: 99%