Organometallphosphin-substituierte Übergangsmetallkomplexe, XIX [1] Carbonyl-dinitrosyl-organometallphosphin-eisen-Komplexe / Organometalphosphine-substituted Transition Metal Complexes, XIX [1] Carbonyl Dinitrosyl Organometalphosphine Iron Complexes

Abstract

<jats:title>Abstract</jats:title><jats:p> The reactions of dicarbonyl dinitrosyl iron with tri-tert-butylphosphine, di(feri-butyl)-trimethylsilyl-, -germyl-, -stannyl-phosphine, tert-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl)phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl)phosphine result in the elimination of one CO ligand and the formation of the corresponding carbonyl dinitrosyl organometalphosphine iron complexes. The IR, <jats:sup>1</jats:sup>H, <jats:sup>31</jats:sup>P, <jats:sup>13</jats:sup>C, and <jats:sup>119</jats:sup>Sn NMR spectra of the new complexes are reported and discussed.</jats:p>