Organoimido-polyoxometalates as polymer pendants

Moore, Aaron R.; Kwen, Hai-Doo; Beatty, Alicia M.; Maatta, Eric A.

doi:10.1039/b005022i

Cited by 133 publications

(115 citation statements)

References 8 publications

(4 reference statements)

Supporting

Mentioning

110

Contrasting

Unclassified

Order By: Relevance

“…17) Powder X-ray diffraction data indicate isolation of a potential polymorph, when compared to the X-ray powder pattern calculated from the published single crystal structure. (See.…”

Section: Resultsmentioning

confidence: 99%

“…14)16) Previous examples have focused on imidization by 2,6-or 2,4-functionalized anilines, with reaction times (at reflux) in the range of 1224 h. Previous imidizations have relied on isocyanate or iminophosphorane precursors with multi-day reaction times, 17) so these reports represent a significant step forward in providing access to polyoxometalate hybrids.…”

Section: Introductionmentioning

confidence: 99%

“…5) The combination of electrochemical activity and dianionic character hint at significant opportunities in the area of electrochemical cells, particularly if the better film forming characteristics of hybrid polymers can be accessed. 17) The addition of a polymerizable styryl ligand to a hexamolybdate cluster ( Fig. 1) and the demonstration of its free radical polymerization by the Maatta group cracked open the door to an enormous variety of polymeric hybrid polyoxometalate imides.…”

Section: Introductionmentioning

confidence: 99%

“…17) The synthesis reported herein utilizes recent synthetic developments with a precipitation based work-up to provide facile access to monomer 1 in a matter of a few hours, opening opportunities for a wider set of polymer and materials chemistry researchers (Scheme 1).…”

Section: Introductionmentioning

confidence: 99%

“…1) and the demonstration of its free radical polymerization by the Maatta group cracked open the door to an enormous variety of polymeric hybrid polyoxometalate imides. 17) This Note will document a concise route to rapidly synthesize a readily polymerizable, styryl-polyoxometalate monomer from low cost precursor materials using recent discoveries in the area of polyoxometalate imidization.…”

Section: Introductionmentioning

confidence: 99%

See 4 more Smart Citations

A direct synthesis of the styrylimido derivative of the hexamolybdate dianion

Fischer

Stampka

Roll

2015

J. Ceram. Soc. Japan

View full text Add to dashboard Cite

Polyoxometalate imides represent an area of materials chemistry research that recently has seen exciting exploration. Consisting of polyhedral metal-oxide clusters covalently coupled to organic ligands, they possess a combination of electrochemical activity and poly-anionic character hint. These characteristics suggest significant opportunities in the area solid-electrolytes, particularly if the typically good film forming characteristics of hybrid polymers can be accessed. The incorporation of a styryl group allows for hybrid polymers to be synthesized through free radical methods, producing hybrid materials that offer that an enormous number of opportunities to both materials scientists and engineers. This Note will document a concise route to quickly produce the readily polymerizable, styrylimido-hexamolybdate monomer from low cost precursor materials by leveraging recent advances and address some of the synthetic challenges found.

show abstract

“…17) Powder X-ray diffraction data indicate isolation of a potential polymorph, when compared to the X-ray powder pattern calculated from the published single crystal structure. (See.…”

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%