1998
DOI: 10.2172/650142
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Organic tanks safety program, FY97 waste aging studies. Revision 1

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Cited by 9 publications
(35 citation statements)
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“…Tank waste and solubility studies have shown that the results are dependent on tank waste type. In other words, for tanks with different fill histories, the dominant organic anions in the waste may be primarily glycolate, primarily acetate, or a combination of both anions , Camaioni et al, 1998, Barney 1997, Ashby et al, 1994 For C-104 analyses, no acetate/glycolate peak was detected in the supernatants or solids above the MDL. In view of the fact that acetate and glycolate have similar response factors, the reported acetate MDL can be used to bound the upper acetate/glycolate concentration.…”
Section: Analysis Resultsmentioning
confidence: 99%
“…Tank waste and solubility studies have shown that the results are dependent on tank waste type. In other words, for tanks with different fill histories, the dominant organic anions in the waste may be primarily glycolate, primarily acetate, or a combination of both anions , Camaioni et al, 1998, Barney 1997, Ashby et al, 1994 For C-104 analyses, no acetate/glycolate peak was detected in the supernatants or solids above the MDL. In view of the fact that acetate and glycolate have similar response factors, the reported acetate MDL can be used to bound the upper acetate/glycolate concentration.…”
Section: Analysis Resultsmentioning
confidence: 99%
“…The thermal and radiolytic oxidation of organic compounds in simulated Hanford wastes have been studied extensively (Ashby et al 1992(Ashby et al , 1993(Ashby et al ,1994Barefield et al 1995Barefield et al , 1996Bryan et al 1993;Bryan and Pederson 1994;Camaioni et al 1995Camaioni et al ,1996Camaioni et al ,1997Delegard 1980Delegard ,1987Meisel et al 1991aMeisel et al , 1991bMeisel et al , 1992Meisel et al , 1993Meisel et al , 1997. The reactivity order for thermal degradation of the complexants, which encompasses all the pathways for the decomposition of the organic constituents in the waste in the absence of radiation, has been given as (Camaioni et al 1996):…”
Section: General Features Of Organic Reactions In Hanford Wastesmentioning
confidence: 99%
“…Additional radiolytic pathways are available for the aging of complexants and solvents in Hanford wastes (Meisel et al 1991a(Meisel et al , 1991b(Meisel et al , 1992(Meisel et al , 1993(Meisel et al ,1997Camaioni et al 1995Camaioni et al , 1996Camaioni et al , 1997. Products of water radiolysis include the hydrated electron, hydrogen atom, hydroxide radical, hydrogen dioxide radical, and hydrogen ion (Spinks and Woods 1990).…”
Section: General Features Of Organic Reactions In Hanford Wastesmentioning
confidence: 99%
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