Organic Compounds of Polyvalent Iodine.

Sandin, Rueben B.

doi:10.1021/cr60103a001

Cited by 60 publications

(35 citation statements)

References 55 publications

(74 reference statements)

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“…In this L L case, those compounds RILz with the smallest equilibrium constants will be the most stable. Some specific examples are given in equations (2)- (5). For most of these reactions, equilibrium measurements have either not been made or the reactions have not yet been directly observcd.…”

Section: Organoiodinanes: Stability and Occurrencementioning

confidence: 99%

Hypervalent halogen compounds

Koser¹

Halides, Pseudo-Halides and Azides: Vol. 1 (1983)

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Section: Organoiodinanes: Stability and Occurrencementioning

confidence: 99%

Hypervalent halogen compounds

Koser¹

Halides, Pseudo-Halides and Azides: Vol. 1 (1983)

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“…There are repeated reports in the literature [84,85] that diaryliodonium halides are thermally unstable on prolonged heating, hence their recrystallizations should be carried out as quickly as possible from boiling solvents. Analytical purity of the iodonium bromides and iodides obtained by us was achieved by quick dissolving small crude samples in boiling MeOH, followed by the immediate hot filtration neglecting the losses, and rapid cooling.…”

Section: Short-cut Syntheses Of Diaryliodonium Salts With Chromium(vimentioning

confidence: 99%

Organic Iodine(I, III, and V) Chemistry: 10 Years of Development at the Medical University of Warsaw, Poland

Skulski

2000

Molecules

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This review reports some novel (or considerably improved) methods for the synthesis of aromatic iodides, (dichloroiodo)arenes, (diacetoxyiodo)arenes, iodylarenes and diaryliodonium salts, as well as some facile, oxidative anion metatheses in crude diaryliodonium halides and, for comparison, potassium halides. All these new results were obtained in our laboratory over the past decade (1990-2000). A full list of our papers dealing with the organic iodine(I, III and V) chemistry, covering exlusively the aromatic derivatives, is also provided.

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“…For example, both iodoso compounds (RIO) and iodoxy compounds (RIOt) react quantitatively with iodides in acid solution to yield the parent iodo compound and free iodine (1).…”

Section: Organic Positive Iodine Compoundsmentioning

confidence: 99%

“…1 and 2, along with the polarographic data of organic positive-iodine compounds in the literature (14), indicate that the reduction of iodoso and iodoxybenzene takes place according to Eq. [1] and [2].…”

Section: Ci-mentioning

confidence: 99%